1062222-96-1

Basic information

• Product Name: Benzene, 1,1',1'',1'''-(1,2-ethenediylidene)tetrakis[4-(2-broMoethoxy)-
• Synonyms: Benzene, 1,1',1'',1'''-(1,2-ethenediylidene)tetrakis[4-(2-broMoethoxy)-;1,1,2,2-tetrakis(4-(2-broMoethoxy)phenyl)ethene;1,1',1'',1'''-(1,2-ethenediylidene)tetrakis[4-(2-broMoethoxy)-Benzene
• CAS NO: 1062222-96-1
• Molecular Formula: C₃₄H₃₂Br₄O₄
• Molecular Weight: 824.23148
• Mol File: 1062222-96-1.mol

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Benzene, 1,1',1'',1'''-(1,2-ethenediylidene)tetrakis[4-(2-broMoethoxy)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,1',1'',1'''-(1,2-ethenediylidene)tetrakis[4-(2-broMoethoxy)-(1062222-96-1)
• EPA Substance Registry System: Benzene, 1,1',1'',1'''-(1,2-ethenediylidene)tetrakis[4-(2-broMoethoxy)-(1062222-96-1)

Safety Data

• Hazardous Substances Data: 1062222-96-1(Hazardous Substances Data)

Usage

Uses

Used in Organic Synthesis:
Benzene, 1,1',1'',1'''-(1,2-ethenediylidene)tetrakis[4-(2-broMoethoxy)is utilized as a key intermediate in organic synthesis for the preparation of a variety of organic molecules. Its reactivity allows it to participate in numerous chemical reactions, facilitating the creation of new compounds and materials.
Used in Chemical Research:
In the field of chemical research, this compound is employed as a valuable tool for studying organic chemistry and molecular interactions. Its unique structure and properties provide insights into the behavior of similar benzene derivatives and contribute to the understanding of chemical bonding and reactions.
Used in Pharmaceutical Industry:
Although not explicitly mentioned in the provided materials, given its reactivity and structural features, Benzene, 1,1',1'',1'''-(1,2-ethenediylidene)tetrakis[4-(2-broMoethoxy)could potentially be used in the pharmaceutical industry as a precursor for the development of new drugs or as a component in drug delivery systems, due to its ability to form various organic molecules.
Used in Material Science:
Similarly, while not specified in the materials, the compound's properties might also make it suitable for applications in material science, where it could be used to develop new materials with specific properties, such as improved stability or reactivity, depending on the needs of various industries.

Upstream product

• 288248-52-2 4,4’-bis(2-bromoethoxy)benzophenone 
• 119301-59-6 tetra(p-hydroxyphenyl)ethylene 
• 106-93-4 ethylene dibromide 

Downstream Products

• 1373870-33-7 C₄₂H₄₄O₈S₄ 
• 1313513-57-3 C₃₄H₃₂N₁₂O₄ 

Relevant articles and documents

Label-free fluorescent probing of G-quadruplex formation and real-time monitoring of DNA folding by a quaternized tetraphenylethene salt with aggregation-induced emission characteristics

Biosensing processes such as molecular beacons require non-trivial effort to covalently label or mark biomolecules. We report here a label-free DNA assay system with a simple dye with aggregation-induced emission (AIE) characteristics as the fluorescent bioprobe. 1,1,2,2-Tetrakis[4-(2-bromoethoxy)phenyl]ethene is nonemissive in solution but becomes highly emissive when aggregated. This AIE effect is caused by restriction of intramolecular rotation, as verified by a large increase in the emission intensity by increasing viscosity and decreasing temperature of the aqueous buffer solution of 1,1,2,2-tetrakis[4-(2- triethylammonioethoxy)phenyl]ethene tetrabromide (TTAPE). When TTAPE is bound to a guanine-rich DNA strand (G1) via electrostatic attraction, its intramolecular rotation is restricted and its emission is turned on. When a competitive cation is added to the G1 solution, TTAPE is detached and its emission is turned off. TTAPE works as a sensitive poststaining agent for Polyacrylamide) gel electrophoresis (PAGE) visualization of G1. The dye is highly affinitive to a secondary structure of G1 called the G-quadruplex. The bathochromic shift involved in the G1 folding process allows spectral discrimination of the G-quadruplex from other DNA structures. The strong affinity of TTAPE dye to the G-quadruplex structure is associated with a geometric fit aided by the electrostatic attraction. The distinct AIE feature of TTAPE enables real-time monitoring of folding process of G1 in the absence of any pre-attached fluorogenic labels on the DNA strand. TTAPE can be used as a K+ ion biosensor because of its specificity to K+-induced and -stabilized quadruplex structure.

Cucurbit[7]uril-tetraphenylethene host-guest system induced emission activity

A host-guest complex was successfully constructed from cucurbit[7]uril (Q[7]) and quaternary ammonium-modified tetraphenylethene derivative, 1,1,2,2-tetrakis{2-[2-(N,N,N-trimethylammonium)ethyoxyl]phenyl}-tetraphenylethene bromide (TAPET), and characteriz

Tetraphenyl ethylene bridged tetrabenzimidazole salt and preparation method and application thereof

The invention discloses tetraphenyl ethylene bridged tetrabenzimidazole salt and a preparation method and an application thereof. According to the invention, 4,4'-dihydroxy benzophenone is taken as araw material, is subjected to Mc Murry reaction to obtai

Water-soluble AIE luminogens for monitoring and retardation of fibrillation of amyloid proteins

Compounds that exhibit aggregation induced emission (AIE), and more particularly to water-soluble conjugated polyene compounds that exhibit aggregation induced emission. The conjugated polyene compounds can be used as bioprobes for DNA detection, G-quadru

Investigating the effects of side chain length on the AIE properties of water-soluble TPE derivatives

The emissive properties of fluorophores in aggregated state are important for the development of bio-sensors or bio-imaging reagents. So three water-soluble TPE derivatives with different lengths of side chains have been synthesized and we investigated the effects of side chains on aggregation-induced emission (AIE) properties in the aggregated states. The results indicate that side chains on the fluorophores play a pivotal role in their emission in aggregated state mediated by heparin or solid state, because the coplanarity of these TPE derivatives was affected by side chains. The rates of radiative decay kf and non-radiative decay knr have been obtained through the quantum yields and lifetime, and a larger k f and smaller knr were present for compound TPE-C4N, suggesting that the aggregated TPE-C4N should posses the most remarkable fluorescent property.

WATER-SOLUBLE AIE LUMINOGEN FOR MONITORING AND RETARDATION OF AMYLOID FIBRILLATION OF INSULIN

The presently described subject matter is directed to a water-soluble conjugated polyene compound and the derivatives thereof that exhibit aggregation induced emission, as well as any water dispersible, fluorescent, polymeric microparticles, nanoparticles, and/or pharmaceutical composition comprising the water-soluble conjugated polyene compound and/or the derivatives thereof. Also provided are methods of making and using the compound, derivatives and particles of the presently described subject matter. The presently described water-soluble conjugated polyene compound are useful as bioprobes for the detection of biomacromolecules, in the manufacture of sensors, in monitoring and retarding formation of amyloid protein fibril in vitro and in vivo, and in developing anti-cancer drugs.