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High quality 1,2-Dibromoethane supplier in China CAS NO.106-93-4
Cas No: 106-93-4
No Data 10 Gram 500 Kilogram/Month Changchun Artel lmport and Export trade company Contact Supplier
1,2-Dibromoethane
Cas No: 106-93-4
USD $ 1.0-2.0 / Metric Ton 1 Metric Ton 100 Metric Ton/Week Hebei yanxi chemical co.,LTD. Contact Supplier
1,2-Dibromoethane
Cas No: 106-93-4
No Data 1 Kilogram 20 Metric Ton/Week Henan Allgreen Chemical Co.,Ltd Contact Supplier
1,2-Dibromoethane
Cas No: 106-93-4
USD $ 2.0-3.0 / Kilogram 1 Kilogram 50 Metric Ton/Day EAST CHEMSOURCES LIMITED Contact Supplier
Amadis Chemical offer CAS#106-93-4;CAT#A15094
Cas No: 106-93-4
No Data 10 Milligram Amadis Chemical Co., Ltd. Contact Supplier
Ethylene dibromide
Cas No: 106-93-4
No Data No Data No Data Chemwill Asia Co., Ltd. Contact Supplier
1,2-Dibromoethane
Cas No: 106-93-4
USD $ 1.0-1.0 / Kilogram 1 Kilogram 1000 Kilogram/Month Enke Pharma-tech Co.,Ltd. (Cangzhou, China ) Contact Supplier
1,2-Dibromoethane CAS: 106-93-4
Cas No: 106-93-4
USD $ 1.0-2.0 / Metric Ton 5 Metric Ton 1000 Metric Ton/Year Henan Sinotech Import&Export Corporation Contact Supplier
TIANFU CHEM 106-93-4 1,2-Dibromoethane
Cas No: 106-93-4
USD $ 200.0-200.0 / Kilogram 1 Kilogram 10 Metric Ton/Month Henan Tianfu Chemical Co., Ltd. Contact Supplier
dibromoethane 99.9% Purity.High Quality,Lower Price CAS NO.106-93-4
Cas No: 106-93-4
No Data 10 Gram Metric Ton/Day Jilin Tely Imp.& Exp.Co., Ltd. Contact Supplier

106-93-4 Usage

Purification Methods

Wash the dibromide with conc HCl or H2SO4, then water, aqueous NaHCO3 or Na2CO3, more water, and dry it with CaCl2. Fractionally distil it. Alternatively, keep in daylight with excess bromine for 2hours, then extract with aqueous Na2SO3, wash with water, dry with CaCl2, filter and distil. It can also be purified by fractional crystallisation by partial freezing. Store it in the dark. [Beilstein 1 H 90, 1 I 28, 1 II 61, 1 III 182, 1 IV 158.]

Trade name

AADIBROOM®; EDB-85; FUMO-GAS®; ISCOBROME D®; KOPFUME®; NEFIS®; NEPHIS®; SOILFUME®; UNIFUME®

General Description

1,2-dibromomethane is a heavy, colourless liquid with a mild sweet odour, like chloroform. Ethylene dibromide is incompatible with strong oxidisers, magnesium, alkali metals, and liquid ammonia. Ethylene dibromide is soluble in alcohols, ethers, acetone, benzene, and most organic solvents and slightly soluble in water. Ethylene dibromide was once of dominant use, although its use has faded as an additive in leaded gasoline.
Ethylene dibromide (1,2-dibromoethane) reacts with lead residues to generate volatile lead bromides. Ethylene dibromide (1,2-dibromoethane) reacts with lead residues to generate volatile lead bromides. It has been used as a pesticide in soil and various crops. Most of the uses of ethylene dibromide have been stopped in the United States; however, it is still used as a fumigant for treatment of logs for termites and beetles, for the control of moths and beehives, and as a preparation for dyes and waxes. Because of limitations in epidemiological study evidences for ethylene dibromide as a human carcinogen is inconclusive. In 1984, the U.S. EPA imposed a ban on its use as a soil and grain fumigant.

Air & Water Reactions

Slightly soluble in water. May react slowly with moisture.

Health Hazard

Local inflammation, blisters and ulcers on skin; irritation in lungs and organic injury to liver and kidneys; may be absorbed through skin.

Reactivity Profile

1,2-Dibromoethane slowly decomposes in the presence of light and heat. Turns brown upon exposure to light. Corrosive to iron and other metals. May decompose upon contact with alkalis. Incompatible with oxidizing agents. Reacts with sodium, potassium, calcium, powdered aluminum, zinc, magnesium and liquid ammonia. May attack some plastics, rubber and coatings. May poison platinum catalysts [Hawley]. Reacts as an alkylating agent .

Uses

Soil and grain fumigant; as lead scavenger in anti-knock gasolines. Most of the uses of ethylene dibromide have been stopped in the United States; however, it is still used as a fumigant for treatment of logs for termites and beetles, for the control of moths and beehives, and as a preparation for dyes and waxes.

Chemical Properties

A clear colorless liquid with a sweetish odor. Density 18.1 lb /gal. Slightly soluble in water. Soluble in most organic solvents and thinners. Noncombustible. Very toxic by inhalation, skin absorption or ingestion. Used as a solvent, scavenger for lead in gasoline, grain fumigant and in the manufacture of other chemicals.

Agricultural Uses

Fumigant, Nematicide: Not approved for use in EU countries. Not registered for use in the U.S. Persons whose clothing or skin is contaminated with liquid ethylene dibromide (above 10°C) can secondarily contaminate others by direct contact or through off-gassing vapor. Ethylene dibromide was used extensively as a pesticide and an ingredient of soil, vegetable, fruit, and grain fumigant formulations. Still used in India, South Africa and other countries. There are 15 global suppliers.

Definition

ChEBI: A bromoalkane that is ethane carrying bromo substituents at positions 1 and 2. It is produced by marine algae.
InChI:InChI=1/C2H4Br2/c3-1-2-4/h1-2H2

106-93-4SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 10, 2017

Revision Date: Aug 10, 2017

1.Identification

1.1 GHS Product identifier

Product name 1,2-dibromoethane

1.2 Other means of identification

Product number -
Other names Ethane, 1,2-dibromo-

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only. Volatile organic compounds
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:106-93-4 SDS

106-93-4Synthetic route

ethane
74-84-0

ethane

ethylene dibromide
106-93-4

ethylene dibromide

Conditions
ConditionsYield
With 2AlBr3*CBr4; bromine at 55 - 65℃; for 18h;100%
With 2AlBr3*CBr4; bromine at 55 - 65℃; for 18h; Product distribution; Mechanism; different times;100%
ethene
74-85-1

ethene

ethylene dibromide
106-93-4

ethylene dibromide

Conditions
ConditionsYield
With bromine; iodobis(N,N-diisopropyldithiocarbamato)iron(III) In dichloromethane at 20℃; under 760 Torr;98%
With bromine at -5℃;91%
With bromine
ethene
74-85-1

ethene

di(neopentyloxy)thioxophosphoranesulphenyl bromide
81373-35-5

di(neopentyloxy)thioxophosphoranesulphenyl bromide

A

bis-(O,O-2,2-dimethylpropylthiophosphoryl)disulfide
74895-06-0

bis-(O,O-2,2-dimethylpropylthiophosphoryl)disulfide

B

ethylene dibromide
106-93-4

ethylene dibromide

C

Dithiophosphoric acid S-(2-bromo-ethyl) ester O,O'-bis-(2,2-dimethyl-propyl) ester

Dithiophosphoric acid S-(2-bromo-ethyl) ester O,O'-bis-(2,2-dimethyl-propyl) ester

Conditions
ConditionsYield
In toluene at 0 - 15℃;A 97%
B n/a
C 3%
ethylene glycol
107-21-1

ethylene glycol

ethylene dibromide
106-93-4

ethylene dibromide

Conditions
ConditionsYield
With 1,2-dibromo-1,1,2,2-tetrachloroethane; triphenylphosphine In dichloromethane at 20℃; for 0.15h; Appel Halogenation;96%
With phosphorus; phosphorous; bromine
With sulfuric acid; hydrogen bromide
bromination;
With tetrabutylammomium bromide; triphenylphosphine; 2,3-dicyano-5,6-dichloro-p-benzoquinone In dichloromethane at 20℃;78 % Chromat.
N-bromo-1,8-naphthalenedicarboximide
105089-47-2

N-bromo-1,8-naphthalenedicarboximide

benzene
71-43-2

benzene

A

2-phenylbenzo[de]isoquinoline-1,3-dione
6914-98-3

2-phenylbenzo[de]isoquinoline-1,3-dione

B

ethylene dibromide
106-93-4

ethylene dibromide

Conditions
ConditionsYield
With ethene In dichloromethane at 70℃; Irradiation;A 79%
B 89%
1-Indanol
6351-10-6

1-Indanol

A

inden-1-one
83-33-0

inden-1-one

B

ethylene dibromide
106-93-4

ethylene dibromide

Conditions
ConditionsYield
With air; bromine; sodium carbonate; adogen 464; palladium dichloride Product distribution; multistep reaction: 1.) 1,2-dichloroethane, reflux, 15 h, 2.) CCl4; reactions under var. conditions, reactions of derivatives;A 88%
B n/a
methanol
67-56-1

methanol

Tetracarbonyleisenkomplexe des Ethylens

Tetracarbonyleisenkomplexe des Ethylens

A

Methyl 3-bromopropionate
3395-91-3

Methyl 3-bromopropionate

B

methyl 3-methoxypropionate
3852-09-3

methyl 3-methoxypropionate

C

ethylene dibromide
106-93-4

ethylene dibromide

D

2-Bromoethyl methyl ether
6482-24-2

2-Bromoethyl methyl ether

Conditions
ConditionsYield
With bromine at -80℃; temperature up to 30 deg C;A 67%
B n/a
C n/a
D n/a
1,2-dichloro-ethane
107-06-2

1,2-dichloro-ethane

A

1-Bromo-2-chloroethane
107-04-0

1-Bromo-2-chloroethane

B

ethylene dibromide
106-93-4

ethylene dibromide

Conditions
ConditionsYield
With calcium bromide; tetrahexylammonium bromide at 110℃; for 24h;A 38%
B 53%
ethylene glycol
107-21-1

ethylene glycol

A

ethylene dibromide
106-93-4

ethylene dibromide

B

2-bromoethanol
540-51-2

2-bromoethanol

Conditions
ConditionsYield
With 1,2-dibromo-1,1,2,2-tetrachloroethane; triphenylphosphine In dichloromethane at 20℃; for 0.15h; Appel Halogenation;A 50%
B 45%
ethene
74-85-1

ethene

tetrabutylammonium p-toluenesulfonate
7182-86-7

tetrabutylammonium p-toluenesulfonate

A

2-bromoethyl p-toluenesulfonate
19263-21-9

2-bromoethyl p-toluenesulfonate

B

ethylene dibromide
106-93-4

ethylene dibromide

Conditions
ConditionsYield
With bromine In dichloromethane at 20℃; Product distribution; Mechanism;A 34%
B 51 % Spectr.
With bromine In dichloromethane at 20℃;A 34%
B 51 % Spectr.
With bromine In dichloromethane Ambient temperature;
ethene
74-85-1

ethene

A

2-bromoethyl p-toluenesulfonate
19263-21-9

2-bromoethyl p-toluenesulfonate

B

ethylene dibromide
106-93-4

ethylene dibromide

Conditions
ConditionsYield
With bromine; tetrabutylammonium p-toluenesulfonate In dichloromethane at 20℃;A 34%
B 51 % Spectr.
ethene
74-85-1

ethene

A

ethylene dibromide
106-93-4

ethylene dibromide

B

Dithiophosphoric acid S-(2-bromo-ethyl) ester O,O'-bis-(2,2-dimethyl-propyl) ester

Dithiophosphoric acid S-(2-bromo-ethyl) ester O,O'-bis-(2,2-dimethyl-propyl) ester

Conditions
ConditionsYield
With (tBuCH2O)2P(S)SBr In toluene at 0 - 15℃;A n/a
B 3%
ethyl bromide
74-96-4

ethyl bromide

ethylene dibromide
106-93-4

ethylene dibromide

Conditions
ConditionsYield
With aluminum tri-bromide; bromine at 65 - 70℃;
With bromine at 180℃;
With bromine; iron at 100℃;
Vinyl bromide
593-60-2

Vinyl bromide

ethylene dibromide
106-93-4

ethylene dibromide

Conditions
ConditionsYield
With hydrogen bromide
With hydrogen bromide at 100 - 200℃;
With hydrogen bromide
Vinyl bromide
593-60-2

Vinyl bromide

A

1,1-Dibromoethane
557-91-5

1,1-Dibromoethane

B

ethylene dibromide
106-93-4

ethylene dibromide

Conditions
ConditionsYield
With magnesium hydrosilicate; hydrogen bromide
1,1-Dibromoethane
557-91-5

1,1-Dibromoethane

ethylene dibromide
106-93-4

ethylene dibromide

Conditions
ConditionsYield
at 300 - 320℃;
at 300 - 315℃;
Acetyl bromide
506-96-7

Acetyl bromide

1,2-dibenzyloxyethane
622-22-0

1,2-dibenzyloxyethane

A

Benzyl acetate
140-11-4

Benzyl acetate

B

ethylene dibromide
106-93-4

ethylene dibromide

ethene
74-85-1

ethene

potassium benzenesulfonate
934-55-4

potassium benzenesulfonate

A

benzenesulfonic acid-(2-bromo-ethyl ester)
61855-70-7

benzenesulfonic acid-(2-bromo-ethyl ester)

B

ethylene dibromide
106-93-4

ethylene dibromide

Conditions
ConditionsYield
With water; bromine
chloroethane
75-00-3

chloroethane

ethylene dibromide
106-93-4

ethylene dibromide

Conditions
ConditionsYield
With water; bromine; iron at 100℃;
Acetyl bromide
506-96-7

Acetyl bromide

phenoxyethyl bromide
589-10-6

phenoxyethyl bromide

A

ethylene dibromide
106-93-4

ethylene dibromide

B

Phenyl acetate
122-79-2

Phenyl acetate

1,2-dichloro-ethane
107-06-2

1,2-dichloro-ethane

ethylene dibromide
106-93-4

ethylene dibromide

Conditions
ConditionsYield
With aluminum tri-bromide unterhalb des Siedepunkts;
With aluminum tri-bromide
1-Bromo-2-chloroethane
107-04-0

1-Bromo-2-chloroethane

ethylene dibromide
106-93-4

ethylene dibromide

Conditions
ConditionsYield
With aluminum tri-bromide unterhalb des Siedepunkts;
acetylene
74-86-2

acetylene

ethylene dibromide
106-93-4

ethylene dibromide

Conditions
ConditionsYield
With hydrogen bromide; pyrographite at 220℃;
With metal bromide-contact; hydrogen bromide at 100 - 200℃;
With air; hydrogen bromide; chlorine
dioxane*BBr3=Dioxan*BBr3

dioxane*BBr3=Dioxan*BBr3

A

2-Bromaethyl-metaborat

2-Bromaethyl-metaborat

B

ethylene dibromide
106-93-4

ethylene dibromide

Conditions
ConditionsYield
at 30℃;
octanol
111-87-5

octanol

A

1-bromo-octane
111-83-1

1-bromo-octane

B

ethylene dibromide
106-93-4

ethylene dibromide

Conditions
ConditionsYield
With Bis-(2-bromoethyl)selenium dibromide at 80℃; for 7h; Product distribution; Mechanism; other dialkylselenium dihalides; other alcohols;A 98 % Chromat.
B 75 % Chromat.
ethene
74-85-1

ethene

dichloromethane
75-09-2

dichloromethane

methylcyclopropane
594-11-6

methylcyclopropane

2,2-dimethyl-N-bromoglutarimide
82621-80-5

2,2-dimethyl-N-bromoglutarimide

A

1-bromo-4-butene
5162-44-7

1-bromo-4-butene

B

2,2-dimethylglutarimide
1194-33-8

2,2-dimethylglutarimide

C

bromodichloromethane
75-27-4

bromodichloromethane

D

N-(2-bromoethyl)-3,3-dimethylglutarimide

N-(2-bromoethyl)-3,3-dimethylglutarimide

E

ethylene dibromide
106-93-4

ethylene dibromide

F

cyclopropylcarbinyl bromide
7051-34-5

cyclopropylcarbinyl bromide

Conditions
ConditionsYield
at 15℃; for 1h; Product distribution; Kinetics; Mechanism; Irradiation;A 1.7 % Chromat.
B 50.4 % Chromat.
C 12.8 % Chromat.
D 50.1 % Chromat.
E 2.0 % Chromat.
F 18.0 % Chromat.
ethene
74-85-1

ethene

tetrabutylammonium methanesulfonate
65411-49-6

tetrabutylammonium methanesulfonate

A

2-bromoethyl methanesulfonate
4239-10-5

2-bromoethyl methanesulfonate

B

ethylene dibromide
106-93-4

ethylene dibromide

Conditions
ConditionsYield
With bromine In dichloromethane Ambient temperature;
ethene
74-85-1

ethene

tetrabutylammonium trifluoromethylsulfonate
35895-70-6

tetrabutylammonium trifluoromethylsulfonate

A

2-bromoethyl triflate
103935-47-3

2-bromoethyl triflate

B

ethylene dibromide
106-93-4

ethylene dibromide

Conditions
ConditionsYield
With bromine at -78 - 20℃; various solvents; Yield given. Yields of byproduct given;
ethene
74-85-1

ethene

lithium trifluoromethanesulfonate
33454-82-9

lithium trifluoromethanesulfonate

A

2-bromoethyl triflate
103935-47-3

2-bromoethyl triflate

B

ethylene dibromide
106-93-4

ethylene dibromide

Conditions
ConditionsYield
With bromine at -78 - 20℃; various solvents; Yield given. Yields of byproduct given;
dimethyl amine
124-40-3

dimethyl amine

ethylene dibromide
106-93-4

ethylene dibromide

N,N,N,N,-tetramethylethylenediamine
110-18-9

N,N,N,N,-tetramethylethylenediamine

Conditions
ConditionsYield
In tetrahydrofuran at 0 - 20℃; for 24h;100%
In chloroform at 20℃; for 24h;100%
L-Cysteine
52-90-4

L-Cysteine

ethylene dibromide
106-93-4

ethylene dibromide

S,S'-ethanediyl-bis-L-cysteine
14344-49-1

S,S'-ethanediyl-bis-L-cysteine

Conditions
ConditionsYield
With sodium hydrogencarbonate In ethanol; water at 70 - 90℃; for 1h;100%
With sodium hydrogencarbonate88%
2-hydroxybromobenzene
95-56-7

2-hydroxybromobenzene

ethylene dibromide
106-93-4

ethylene dibromide

1-(2-bromoethoxy)-2-bromobenzene
18800-28-7

1-(2-bromoethoxy)-2-bromobenzene

Conditions
ConditionsYield
With potassium carbonate In acetonitrile at 80℃;100%
With caesium carbonate In acetonitrile at 80℃; for 11h; Inert atmosphere; Schlenk technique;88%
With sodium hydroxide for 6.5h; Etherification; Heating;72%
carbon disulfide
75-15-0

carbon disulfide

ethylene dibromide
106-93-4

ethylene dibromide

acetylacetone
123-54-6

acetylacetone

3-(1,3-dithiolan-2-ylidene)pentane-2,4-dione
2183-30-4

3-(1,3-dithiolan-2-ylidene)pentane-2,4-dione

Conditions
ConditionsYield
With potassium carbonate100%
Stage #1: carbon disulfide; acetylacetone With tetrabutylammomium bromide; potassium carbonate In water at 20℃;
Stage #2: ethylene dibromide In water at 20℃; for 8h;
97%
Stage #1: carbon disulfide; acetylacetone With tetrabutylammomium bromide; potassium carbonate In water at 20℃; for 1h;
Stage #2: ethylene dibromide In water at 20℃; for 8.25h; Further stages.;
97%
ethylene dibromide
106-93-4

ethylene dibromide

ethanethiol
75-08-1

ethanethiol

2,2'-ethane-1,2-diylbissulfanyl-bis-ethanol
5244-34-8

2,2'-ethane-1,2-diylbissulfanyl-bis-ethanol

Conditions
ConditionsYield
With sodium ethanolate In ethanol for 1h; Heating;100%
ethylene dibromide
106-93-4

ethylene dibromide

(1R,2R)-1-(4-Methoxy-phenyl)-2-(3,4,5-trimethoxy-phenyl)-ethane-1,2-diol
205366-80-9

(1R,2R)-1-(4-Methoxy-phenyl)-2-(3,4,5-trimethoxy-phenyl)-ethane-1,2-diol

(2R,3R)-2-(4-Methoxy-phenyl)-3-(3,4,5-trimethoxy-phenyl)-[1,4]dioxane

(2R,3R)-2-(4-Methoxy-phenyl)-3-(3,4,5-trimethoxy-phenyl)-[1,4]dioxane

Conditions
ConditionsYield
With sodium hydroxide; cetyltrimethylammonium chloride100%
sodium ethanolate
141-52-6

sodium ethanolate

ethylene dibromide
106-93-4

ethylene dibromide

para-thiocresol
106-45-6

para-thiocresol

(2-ethoxyethyl)-para-thiocresol
57023-03-7

(2-ethoxyethyl)-para-thiocresol

Conditions
ConditionsYield
Stage #1: para-thiocresol With sodium ethanolate In ethanol at 20℃; Metallation;
Stage #2: ethylene dibromide In ethanol at 20℃; Alkylation;
Stage #3: sodium ethanolate In ethanol Substitution; Heating;
100%
di(pyridin-2-yl)amine
1202-34-2

di(pyridin-2-yl)amine

ethylene dibromide
106-93-4

ethylene dibromide

1-(pyridin-2-yl)-2,3-dihydro-1H-imidazo[1,2-a]pyridinium bromide

1-(pyridin-2-yl)-2,3-dihydro-1H-imidazo[1,2-a]pyridinium bromide

Conditions
ConditionsYield
With N-ethyl-N,N-diisopropylamine for 18h; Heating;100%
ethylene dibromide
106-93-4

ethylene dibromide

tert-butyl 4-hydroxy-5-methoxy-11-azatricyclo[6.2.1.02,7]undeca-2(7),3,5-triene-11-carboxylate

tert-butyl 4-hydroxy-5-methoxy-11-azatricyclo[6.2.1.02,7]undeca-2(7),3,5-triene-11-carboxylate

tert-butyl 4-(2-bromoethoxy)-5-methoxy-11-azatricyclo[6.2.1.02,7]undeca-2(7),3,5-triene-11-carboxylate

tert-butyl 4-(2-bromoethoxy)-5-methoxy-11-azatricyclo[6.2.1.02,7]undeca-2(7),3,5-triene-11-carboxylate

Conditions
ConditionsYield
With potassium hydroxide; tetra(n-butyl)ammonium hydroxide In water at 50℃; for 15h;100%
ethylene dibromide
106-93-4

ethylene dibromide

tert-butyl 4-hydroxy-5-[(naphthalen-1-yl)methoxy]-11-azatricyclo[6.2.1.02,7]undeca-2(7),3,5-triene-11-carboxylate

tert-butyl 4-hydroxy-5-[(naphthalen-1-yl)methoxy]-11-azatricyclo[6.2.1.02,7]undeca-2(7),3,5-triene-11-carboxylate

tert-butyl 4-(2-bromoethoxy)-5-[(naphthalen-1-yl)methoxy]-11-azatricyclo[6.2.1.02,7]undeca-2(7),3,5-triene-11-carboxylate

tert-butyl 4-(2-bromoethoxy)-5-[(naphthalen-1-yl)methoxy]-11-azatricyclo[6.2.1.02,7]undeca-2(7),3,5-triene-11-carboxylate

Conditions
ConditionsYield
With potassium hydroxide; tetra(n-butyl)ammonium hydroxide In water at 50℃; for 15h;100%
ethylene dibromide
106-93-4

ethylene dibromide

tert-butyl 4-hydroxy-5-[(naphthalen-2-yl)methoxy]-11-azatricyclo[6.2.1.02,7]undeca-2(7),3,5-triene-11-carboxylate

tert-butyl 4-hydroxy-5-[(naphthalen-2-yl)methoxy]-11-azatricyclo[6.2.1.02,7]undeca-2(7),3,5-triene-11-carboxylate

tert-butyl 4-(2-bromoethoxy)-5-[(naphthalen-2-yl)methoxy]-11-azatricyclo[6.2.1.02,7]undeca-2(7),3,5-triene-11-carboxylate

tert-butyl 4-(2-bromoethoxy)-5-[(naphthalen-2-yl)methoxy]-11-azatricyclo[6.2.1.02,7]undeca-2(7),3,5-triene-11-carboxylate

Conditions
ConditionsYield
With potassium hydroxide; tetra(n-butyl)ammonium hydroxide In water at 50℃; for 15h;100%
3-Iodophenol
626-02-8

3-Iodophenol

ethylene dibromide
106-93-4

ethylene dibromide

1-(2-bromoethoxy)-3-iodobenzene
626250-32-6

1-(2-bromoethoxy)-3-iodobenzene

Conditions
ConditionsYield
With potassium carbonate In acetone for 48h; Heating;100%
With potassium carbonate In acetone at 55℃;92%
With potassium carbonate In acetone at 0 - 55℃; Inert atmosphere;85%
With potassium carbonate; potassium iodide In acetone at 60℃;69%
Stage #1: 3-Iodophenol With potassium carbonate In N,N-dimethyl-formamide for 0.5h; Inert atmosphere;
Stage #2: ethylene dibromide In N,N-dimethyl-formamide at 20 - 55℃; Inert atmosphere;
38%
1,2-bis(4,5-dihydro-1H-imidazol-1-yl)ethane
55403-02-6

1,2-bis(4,5-dihydro-1H-imidazol-1-yl)ethane

ethylene dibromide
106-93-4

ethylene dibromide

2,3,4,5,6,7,8,8c-octahydro-1H-4a,6a,8a-triaza-2a-azoniacyclopent[fg]acenaphthylene bromide salt

2,3,4,5,6,7,8,8c-octahydro-1H-4a,6a,8a-triaza-2a-azoniacyclopent[fg]acenaphthylene bromide salt

Conditions
ConditionsYield
With potassium carbonate In acetonitrile for 3h; Heating;100%
With potassium carbonate In acetonitrile for 3h; Heating;70%
5-acetyl-7-(3-(4-fluorophenyl)butoxy)-6-hydroxy-4-methylbenzofuran
1017961-91-9

5-acetyl-7-(3-(4-fluorophenyl)butoxy)-6-hydroxy-4-methylbenzofuran

ethylene dibromide
106-93-4

ethylene dibromide

5-acetyl-6-(2-bromoethoxy)-7-(3-(4-fluorophenyl)butoxy)-4-methylbenzofuran

5-acetyl-6-(2-bromoethoxy)-7-(3-(4-fluorophenyl)butoxy)-4-methylbenzofuran

Conditions
ConditionsYield
With caesium carbonate In N,N-dimethyl-formamide at 60℃; for 1.5h;100%
6-bromo-naphthalen-2-ol
15231-91-1

6-bromo-naphthalen-2-ol

ethylene dibromide
106-93-4

ethylene dibromide

2-bromo-6-(2-bromoethoxy)naphthalene
205112-20-5

2-bromo-6-(2-bromoethoxy)naphthalene

Conditions
ConditionsYield
With potassium hydroxide; tetrabutylammomium bromide In water at 100℃; for 3h;100%
With potassium carbonate In acetonitrile at 95℃; for 8h;50%
With potassium carbonate In acetonitrile at 95℃; for 8h;50%
With potassium carbonate In N,N-dimethyl-formamide at 20℃; Inert atmosphere;37.54%
C54H44N2S2
404866-70-2

C54H44N2S2

ethylene dibromide
106-93-4

ethylene dibromide

C56H46N2S2

C56H46N2S2

Conditions
ConditionsYield
With sodium hydroxide; tetrabutylammomium bromide In water for 0.25h;100%
(2,6-difluorophenyl)acetonitrile
654-01-3

(2,6-difluorophenyl)acetonitrile

ethylene dibromide
106-93-4

ethylene dibromide

1-(2,6-difluorophenyl)cyclopropane-1-carbonitrile
124276-65-9

1-(2,6-difluorophenyl)cyclopropane-1-carbonitrile

Conditions
ConditionsYield
With sodium hydroxide; tetrabutylammomium bromide In water Product distribution / selectivity;100%
With sodium hydroxide52%
With sodium hydroxide; tetrabutylammomium bromide In water at 35 - 47℃; for 3.5h;
With N-benzyl-N,N,N-triethylammonium chloride; potassium hydroxide In water at 60 - 65℃; for 6h;
ammonium hexafluorophosphate

ammonium hexafluorophosphate

nitromethane
75-52-5

nitromethane

[(η6-C6Me6)Ru(η3-NH(CH2CH2S)2)]
823807-71-2

[(η6-C6Me6)Ru(η3-NH(CH2CH2S)2)]

ethylene dibromide
106-93-4

ethylene dibromide

[(η6-C6Me6)Ru(η3-S(CH2)2NH(CH2)2S(CH2)2)](PF6)2*MeNO2

[(η6-C6Me6)Ru(η3-S(CH2)2NH(CH2)2S(CH2)2)](PF6)2*MeNO2

Conditions
ConditionsYield
In methanol to soln. Ru complex in MeOH Br(CH2)2Br was added and stirred for 2 h, NH4PF6 was added and stirred for 1 h; react. mixt. was evacuated to dryness, residue was extd. with MeCN, filtered through Celite, evacuated to dryness, residue was dissolved in MeNO2, layered with ether andkept at -30°C for 3 days; elem. anal.;100%
C5(CH3)5Ru(C5H4CH2C4H7NCH2OCH3)

C5(CH3)5Ru(C5H4CH2C4H7NCH2OCH3)

ethylene dibromide
106-93-4

ethylene dibromide

(Sp)-Cp*Ru[1-Br-2-(CH2NC4H7CH2OCH3)C5H3]

(Sp)-Cp*Ru[1-Br-2-(CH2NC4H7CH2OCH3)C5H3]

Conditions
ConditionsYield
With LisBu In diethyl ether; cyclohexane (inert atm.); Ru complex in Et2O cooled to -78°C, treated with LisBu in cyclohexane (1:1.70) at -78°C within 20-30 s, stirred at -78°C for 3.5 h, treated with suspn. of ligand in Et2O, warmed to room temp. within 2.5 h, stirred for; evapd.(vac.), extd.(pentane), filtered (kieselghur), freed of volatiles,elem. anal.;100%
1-methyl-4-(5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyridin-2-yl)piperazine
918524-63-7

1-methyl-4-(5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyridin-2-yl)piperazine

ethylene dibromide
106-93-4

ethylene dibromide

1-methyl-4-(5-vinylpyridin-2-yl)piperazine
1168722-41-5

1-methyl-4-(5-vinylpyridin-2-yl)piperazine

Conditions
ConditionsYield
Stage #1: ethylene dibromide With potassium hydroxide In tetrahydrofuran at 95℃; for 1.16667h; Inert atmosphere; Microwave irradiation;
Stage #2: 1-methyl-4-(5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyridin-2-yl)piperazine With triphenylphosphine; palladium diacetate In tetrahydrofuran; methanol at 95℃; for 1h; Microwave irradiation;
100%
Stage #1: ethylene dibromide With potassium hydroxide In tetrahydrofuran at 95℃; for 1.16667h; Microwave irradiation; Inert atmosphere;
Stage #2: 1-methyl-4-(5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyridin-2-yl)piperazine With palladium diacetate; triphenylphosphine In tetrahydrofuran at 95℃; for 1h; Microwave irradiation; Inert atmosphere;
93%
5-chloro-3-bromo-2-hydroxyacetophenone
59443-15-1

5-chloro-3-bromo-2-hydroxyacetophenone

ethylene dibromide
106-93-4

ethylene dibromide

3'-bromo-2'-(2-bromoethoxy)-5'-chloroacetophenone
1210038-73-5

3'-bromo-2'-(2-bromoethoxy)-5'-chloroacetophenone

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 50℃;100%
1,1,2,5,6,6-hexamethyl-1,6-dihydronaphtho<2,1-b:3,4-b'>dipyrrole
81903-37-9

1,1,2,5,6,6-hexamethyl-1,6-dihydronaphtho<2,1-b:3,4-b'>dipyrrole

ethylene dibromide
106-93-4

ethylene dibromide

2Br(1-)*C22H26N2(2+)

2Br(1-)*C22H26N2(2+)

Conditions
ConditionsYield
at 160℃; for 8h; sealed tube;100%
ethylene dibromide
106-93-4

ethylene dibromide

5-nitro-2H-pyrazole-3-carboxylic acid methyl ester
181585-93-3

5-nitro-2H-pyrazole-3-carboxylic acid methyl ester

methyl 1-(2-bromoethyl)-3-nitro-1H-pyrazole-5-carboxylate
1360057-00-6

methyl 1-(2-bromoethyl)-3-nitro-1H-pyrazole-5-carboxylate

Conditions
ConditionsYield
With caesium carbonate In N,N-dimethyl-formamide at 0 - 100℃; for 4h;100%
Stage #1: 5-nitro-2H-pyrazole-3-carboxylic acid methyl ester With caesium carbonate In N,N-dimethyl-formamide at 98℃; for 0.0833333h;
Stage #2: ethylene dibromide at 0 - 20℃; for 5h;
92%
With potassium carbonate In acetone for 2h; Reflux;77%
With potassium carbonate In acetone for 2h; Product distribution / selectivity; Reflux;63%
With potassium carbonate In acetone at 60℃; for 1h;41.1 mmol
ethyl methyl 2-(3-methylisoxazol-5-yl)acetate

ethyl methyl 2-(3-methylisoxazol-5-yl)acetate

ethylene dibromide
106-93-4

ethylene dibromide

ethyl 1-(3-methylisoxazol-5-yl)cyclopropanecarboxylate
1380090-06-1

ethyl 1-(3-methylisoxazol-5-yl)cyclopropanecarboxylate

Conditions
ConditionsYield
With sodium hydroxide; tetrabutyl ammonium fluoride In toluene at 20℃; for 1h;100%
ethylene dibromide
106-93-4

ethylene dibromide

3-trifluoromethylphenylacetonitrile
2338-76-3

3-trifluoromethylphenylacetonitrile

1-(3-(trifluoromethyl)phenyl)cyclopropane-1-carbonitrile

1-(3-(trifluoromethyl)phenyl)cyclopropane-1-carbonitrile

Conditions
ConditionsYield
Stage #1: 3-trifluoromethylphenylacetonitrile With sodium hydride In N,N-dimethyl-formamide at 0℃; for 0.166667h;
Stage #2: ethylene dibromide In N,N-dimethyl-formamide at 20℃; for 3h;
100%
Estrone
53-16-7

Estrone

ethylene dibromide
106-93-4

ethylene dibromide

3-(2’-bromoethoxy)estra-1,3,5(10)-trien-17-one
191155-58-5

3-(2’-bromoethoxy)estra-1,3,5(10)-trien-17-one

Conditions
ConditionsYield
With sodium hydroxide In tetrahydrofuran; water Reflux;100%
With sodium hydroxide In tetrahydrofuran; water Reflux;84%
diethyl ether
60-29-7

diethyl ether

ethylene dibromide
106-93-4

ethylene dibromide

magnesium bromide diethyl etherate
29858-07-9

magnesium bromide diethyl etherate

Conditions
ConditionsYield
With magnesium Heating;100%
(1,4-diazepan-1-yl)(phenyl)methanone
59939-75-2

(1,4-diazepan-1-yl)(phenyl)methanone

ethylene dibromide
106-93-4

ethylene dibromide

1,1'-ethane-1,2-diylbis(4-benzoyl-1,4-diazepane)

1,1'-ethane-1,2-diylbis(4-benzoyl-1,4-diazepane)

Conditions
ConditionsYield
With sodium hydrogencarbonate In ethanol for 16h; Heating;100%
ethylene dibromide
106-93-4

ethylene dibromide

bis-(2-bromoethyl) disulfide
1002-40-0

bis-(2-bromoethyl) disulfide

Conditions
ConditionsYield
With sodium hydrogensulfide; oxygen In ethanol; water at 76℃; for 8h; Temperature; Reflux;100%

106-93-4Upstream product

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1,2-Dibromoethane (ethylene dibromide; EDB) is a probable human carcinogen that was historically added to leaded gasoline as a scavenger to prevent the build-up of lead oxide deposits in engines. Studies indicate that EDB is present at thousands of past fuel spill sites above its stringent EPA M...detailed

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