106446-23-5Relevant articles and documents
Oxidation of Heterocyclic Nitrogen Ylids to Nitro Heterocycles. Comparison of Dimethyldioxirane with Peracids
Coburn, Michael D.
, p. 1883 - 1884 (2007/10/02)
Oxidation of 3-amino-4-(4-chlorophenyl)furazan (1) and its phosphine imine derivative, 3-(4-chlorophenyl)-4-trioctylphosphiniminofurazan (3), with dimethyldioxirane (DMD) gave 3-(4-chlorophenyl)-4-nitrofurazan (4) as the exclusive product.However, the sulfilimine derivative, 3-(4-chlorophenyl)-4-dimethylsulfiliminofurazan (2), was converted by DMD to the sulfoximine, 3-(4-chlorophenyl)-4-dimethylsulfoximinofurazan (6).These results contrast dramatically with the oxidations of these compounds with peracids.