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118214-15-6

Lithium, [[diphenyl(phenylmethylene)phosphoranyl]phenylmethyl]- is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 118214-15-6 Structure

  • Basic information

    1. Product Name: Lithium, [[diphenyl(phenylmethylene)phosphoranyl]phenylmethyl]-
    2. Synonyms:
    3. CAS NO:118214-15-6
    4. Molecular Formula: C26H22LiP
    5. Molecular Weight: 372.375
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 118214-15-6.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: Lithium, [[diphenyl(phenylmethylene)phosphoranyl]phenylmethyl]-(CAS DataBase Reference)
    10. NIST Chemistry Reference: Lithium, [[diphenyl(phenylmethylene)phosphoranyl]phenylmethyl]-(118214-15-6)
    11. EPA Substance Registry System: Lithium, [[diphenyl(phenylmethylene)phosphoranyl]phenylmethyl]-(118214-15-6)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 118214-15-6(Hazardous Substances Data)

118214-15-6 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 118214-15-6 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,1,8,2,1 and 4 respectively; the second part has 2 digits, 1 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 118214-15:
(8*1)+(7*1)+(6*8)+(5*2)+(4*1)+(3*4)+(2*1)+(1*5)=96
96 % 10 = 6
So 118214-15-6 is a valid CAS Registry Number.

118214-15-6SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 15, 2017

Revision Date: Aug 15, 2017

1.Identification

1.1 GHS Product identifier

Product name lithium,benzylidene-diphenyl-(phenylmethyl)-λ<sup>5</sup>-phosphane

1.2 Other means of identification

Product number -
Other names -

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:118214-15-6 SDS

118214-15-6Relevant articles and documents

Condensation of Lithium Diphenylphosphonium Diylides with Carbonic Anhydride Derivatives. A New One-Pot Synthesis of α,β-Unsaturated Anilides and Amidines.

Cristau, Henri-Jean,Perraud-Darcy, Anne,Ribeill, Yves

, p. 2693 - 2696 (2007/10/02)

Lithium diphenylphosphonium diylides readily attack phenylisocyanate and dicyclohexylcarbodiimide.The formed semi-stabilised ylides bear a metallated amide or amidine functium.Their use in situ as Wittig reagents towards aldehydes and ketones is shown to be a new one-pot, E-stereoselective synthesis for α,β-unsaturated anilides and amidines.Moreover, the corresponding phosphonium salts were isolated.Key Words: lithium phosphonium diylides; pseudo-acylation reaction; Wittig-reaction; vinylic amides and amidines.

Phosphonium-benzylide und Alkali-: Beispiele fuer salzfreie Ylide und korrespondierende Alkalikomplexe

Schmidbaur, Hubert,Deschler, Ulrich,Milewski-Mahrla, Beatrix,Zimmer-Gasser, Beate

, p. 608 - 619 (2007/10/02)

Phosphonium salts R2P(CH2C6H5)2+Br- (with R = CH3, CH2C6H5, or C6H5) were prepared from phosphane precursors with benzyl bromide and converted into the corresponding ylides R2P(CH2C6H5)=CHC6H5 (3a-c).These ylides react with lithiumal

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