42036-72-6

Basic information

• Product Name: Benzene, (1Z)-1-octenyl-
• CAS NO: 42036-72-6
• Molecular Formula: C14H20
• Molecular Weight: 188.313
• Mol File: 42036-72-6.mol
• Article Data: 29

Chemical Properties

• CAS DataBase Reference: Benzene, (1Z)-1-octenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, (1Z)-1-octenyl-(42036-72-6)
• EPA Substance Registry System: Benzene, (1Z)-1-octenyl-(42036-72-6)

Safety Data

• Hazardous Substances Data: 42036-72-6(Hazardous Substances Data)

Upstream product

• 407617-06-5 1,1-dibromo-2-(trimethylsiloxy)octane 
• 103-64-0 bromostyrene 
• 3761-92-0 n-hexylmagnesium bromide 
• 4406-72-8 2-phenyl[1,3,2]dioxaborolane 
• 111-66-0 oct-1-ene 
• 588-73-8 (Z)-β-bromostyrene 
• 75456-64-3 1-Methoxyoct-1-ene 
• 100-58-3 phenylmagnesium bromide 
• 64275-73-6 (Z)-oct-5-en-1-ol 
• 10521-96-7 styryl acetate 
• 626-62-0 Cyclohexyl iodide 
• 536-74-3 phenylacetylene 
• 111-27-3 hexan-1-ol 
• 17376-04-4 2-phenethyl iodide 

Downstream Products

• 109786-55-2 threo-1-phenyl-1,2-octanediol 
• 109786-55-2 erythro-1-phenyl-1,2-octanediol 
• 28665-60-3 (E)-1-phenyl-1-octene 

Relevant articles and documents

Dilithium Amides as a Modular Bis-Anionic Ligand Platform for Iron-Catalyzed Cross-Coupling

Dilithium amides have been developed as a bespoke and general ligand for iron-catalyzed Kumada-Tamao-Corriu cross-coupling reactions, their design taking inspiration from previous mechanistic and structural studies. They allow for the cross-coupling of alkyl Grignard reagents with sp2-hybridized electrophiles as well as aryl Grignard reagents with sp3-hybridized electrophiles. This represents a rare example of a single iron-catalyzed system effective across diverse coupling reactions without significant modification of the catalytic protocol, as well as remaining operationally simple.

Dinuclear cobalt complex-catalyzed stereodivergent semireduction of alkynes: Switchable selectivities controlled by H2O

Catalytic semireduction of internal alkynes to alkenes is very important for organic synthesis. Although great success has been achieved in this area, switchable Z/E stereoselectivity based on a single catalyst for the semireduction of internal alkynes is a longstanding challenge due to the multichemo- and stereoselectivity, especially based on less-expensive earth-abundant metals. Herein, we describe a switchable semireduction of alkynes to (Z)- or (E)-alkenes catalyzed by a dinuclear cobalt complex supported by a macrocyclic bis pyridyl diimine (PDI) ligand. It was found that cis-reduction of the alkyne occurs first and the Z-E alkene stereoisomerization process is formally controlled by the amount of H2O, since the concentration of H2O may influence the catalytic activity of the catalyst for isomerization. Therefore, this protocol provides a facile way to switch to either the (Z)- or (E)-olefin isomer in a single transformation by adjusting the amount of water.

Covalent Organic Framework as a Heterogeneous Ligand for the Regioselective Oxidative Heck Reaction

A simple imine-based covalent organic framework (COF) as heterogeneous ligand for PdII-promoted Heck reaction is reported. Good regioselectivity for a wide range of electronically unbiased olefins is obtained (linear/branched >100:1 in most cases). Related tests and density functional theory calculations are used to explore the reason underlying the high selectivity. This research opens a route for COF as an intriguing platform to control regioselectivity catalysis.