119065-12-2Relevant articles and documents
Stereoselective synthesis of the C1-C13 segment of dolabelide B
Keck, Gary E.,McLaws, Mark D.
, p. 4911 - 4914 (2005)
The efficient construction of the C1-C13 segment of dolabelide B is described. A key element of the synthesis entails BITIP catalyzed asymmetric methallylation to establish the C7 stereocenter, which was then used to direc
ALDOL ADDITION REACTIONS OF CHIRAL CROTONATE IMIDES
Evans, David A.,Sjogren, Eric B.,Bartroli, Javier,Dow, Robert L.
, p. 4957 - 4960 (2007/10/02)
Aldol addition reaction of the crotonate imides 1 and 2 affords the adducts 3 and 4 with high diastereoselection.Subsequent removal of the chiral auxiliary can be effected in good yield to provide a number of synthetically useful intermediates.