144665-39-4Relevant academic research and scientific papers
Total synthesis of the ionophore antibiotic CP-61,405 (routiennocin)
Diez-Martin, David,Kotecha, Nikesh R.,Ley, Steven V.,Mantegani, Sergio,Menendez, J. Carlos,Organ, Helen M.,White, Andrew D.,Banks, Bernard J.
, p. 7899 - 7938 (2007/10/02)
The total synthesis of the spiroketal ionophore antibiotic routiennocin 1 (CP-61,405) employing π-allyltricarbonyl iron lactone complexes is described. These complexes were used as precursors for the preparation of substituted 2-phenylsulphonyl pyrans whi
HYDROFORMYLATION AS A SIMPLE AND EFFICIENT ONE CARBON HOMOLOGATION OF HOMOALLYLIC ALCOHOLS. SYNTHESIS OF PRELOG-DJERASSI LACTONE.
Wuts, P.G.M.,Obrzut, M.L.,Thompson, P.A.
, p. 4051 - 4054 (2007/10/02)
A hydroformylation oxidation sequence is described for the efficient conversion of homoallylic alcohols to δ-lactones.The methodology is applied to the synthesis of Prelog-Djerassi lactone
