1201411-20-2Relevant articles and documents
Nanoheterogeneous catalysis in electrochemically induced olefin perfluoroalkylation
Dudkina, Yulia B.,Gryaznova, Tatyana V.,Osin, Yuri N.,Salnikov, Vadim V.,Davydov, Nikolay A.,Fedorenko, Svetlana V.,Mustafina, Asia R.,Vicic, David A.,Sinyashin, Oleg G.,Budnikova, Yulia H.
supporting information, p. 8833 - 8838 (2015/05/20)
Ni-catalyzed electroreductive olefin perfluoroalkylation affords both monomeric and dimeric products depending on the reaction media. Recycling of the catalyst can be achieved by immobilization of a (bpy)NiBr2 complex on silica nanoparticles decorated with anchoring amino-groups. Switching the homogeneous and heterogeneous catalysts is found to be one more factor to control the product ratio. This catalytic technique is both green and atom economical and combines the advantages of nanoheterogeneous catalysis and electrocatalysis.
Electrocatalytic fluoroalkylation of olefins
Mikhaylov,Gryaznova,Budnikova,Sinyashin
experimental part, p. 1918 - 1920 (2011/07/08)
Under electrocatalysis conditions, the perfluoroalkylation of α-methylstyrene by the nickel complex NiBr2bipy proceeds with the formation of dimeric products of addition of perfluoroalkyl radicals to the double bond.
