12120-15-9

Basic information

• Product Name: ETHYLENEBIS(TRIPHENYLPHOSPHINE)PLATINUM(0)
• Synonyms: ETHYLENEBIS(TRIPHENYLPHOSPHINE)PLATINUM(0);Ethylenebis(triphenylphosphine)Platinum(II);bis(triphenylphosphine)(ethylene)platinum(0);Ethylenebis(triphenylphosphine)platinum(0),98%
• CAS NO: 12120-15-9
• Molecular Formula: C₃₈H₃₄P₂Pt
• Molecular Weight: 747.7
• Product Categories: Catalysis and Inorganic Chemistry;Chemical Synthesis;Platinum
• Mol File: 12120-15-9.mol

Chemical Properties

• Melting Point: 127-131 °C
• Boiling Point: 360°C at 760 mmHg
• Flash Point: 181.7°C
• Appearance: /
• Vapor Pressure: 4.74E-05mmHg at 25°C
• Storage Temp.: Refrigerator (+4°C)
• CAS DataBase Reference: ETHYLENEBIS(TRIPHENYLPHOSPHINE)PLATINUM(0)(CAS DataBase Reference)
• NIST Chemistry Reference: ETHYLENEBIS(TRIPHENYLPHOSPHINE)PLATINUM(0)(12120-15-9)
• EPA Substance Registry System: ETHYLENEBIS(TRIPHENYLPHOSPHINE)PLATINUM(0)(12120-15-9)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 37/39-26
• WGK Germany: 3
• Hazardous Substances Data: 12120-15-9(Hazardous Substances Data)

Usage

Uses

Used in Chemical Synthesis:
ETHYLENEBIS(TRIPHENYLPHOSPHINE)PLATINUM(0) is used as a catalyst for hydrosilation, a chemical reaction that involves the addition of a silicon-hydrogen bond to an unsaturated compound, such as an alkene or alkyne. This reaction is important in the synthesis of various organic and organosilicon compounds.
Used in Ligand Exchange Reactions:
ETHYLENEBIS(TRIPHENYLPHOSPHINE)PLATINUM(0) is used as a nucleophilic metal species for ligand exchange with alkenes and alkynes. This process allows for the modification of the metal center's coordination environment, which can be useful in the development of new catalysts and coordination complexes.
Used in Oxidative Addition Reactions:
ETHYLENEBIS(TRIPHENYLPHOSPHINE)PLATINUM(0) is used as a reagent for oxidative addition to activated C-X bonds, where X can be a halogen, oxygen, or another electronegative atom. This reaction is a key step in many catalytic processes, including cross-coupling and C-C bond formation.
Used in Pharmaceutical Industry:
ETHYLENEBIS(TRIPHENYLPHOSPHINE)PLATINUM(0) can be used as a catalyst or reagent in the synthesis of pharmaceutical compounds, particularly those involving the formation of C-C or C-X bonds. Its ability to facilitate ligand exchange and oxidative addition reactions can be valuable in the development of new drugs and drug candidates.
Used in Materials Science:
In the field of materials science, ETHYLENEBIS(TRIPHENYLPHOSPHINE)PLATINUM(0) can be employed as a catalyst or reagent in the synthesis of advanced materials, such as polymers, nanoparticles, and other functional materials. Its versatility in facilitating various types of chemical reactions makes it a valuable tool in the development of new materials with unique properties and applications.

InChI:InChI=1/2C18H15P.C2H4.Pt/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2;/h2*1-15H;1-2H2;

Upstream product

• 13517-35-6 tris(triphenylphosphine)platinum⁽⁰⁾ 
• 74-85-1 ethene 
• 10199-34-5 bis(triphenylphosphine)platinum(II) dichloride 
• 16940-66-2 sodium tetrahydroborate 
• 10199-34-5 cis-dichlorobis(triphenylphosphine)platinum(II) 
• 603-35-0 triphenylphosphine 
• 12130-66-4 bis(cycloocta-1,5-diene)platinum⁽⁰⁾ 

Downstream Products

• 10199-34-5 bis(triphenylphosphine)platinum(II) dichloride 
• 14221-02-4 tetrakis(triphenylphosphine)platinum 
• 16841-99-9 trans-chlorohydridobis(triphenylphosphine)platinum(II) 
• 183903-82-4 {(CH₃)3Sn}2Pt{P(C₆H₅)3}2 
• 480990-51-0 cis-[Pt(H)(triphenylphosphine)2(silafluorenyl)] 
• 891486-24-1 cis-[Pt(triphenylphosphine)2(silafluorenyl)2] 
• 891486-26-3 [Pt(triphenylphosphine)2((SiC₁₂H₈)2O)] 
• 778640-66-7 [(triphenylphosphine)2PtH(μ-3,7-di-tert-butylsilafluorenyl)(μ-η2-3,7-di-tert-butylsilafluorenyl)Pt(triphenylphosphine)] 
• 119818-84-7 (P(C₆H₅)3)2Pt(CH₃BrCCH₂) 
• 60038-75-7 triphenylphosphanebis(η2-vinyl)platinum(O) 
• 891486-30-9 [Pt(triphenylphosphine)2((SiC₂₀H₂₄)2O)] 
• 102412-05-5 (selenito-O,O')bis(triphenylphosphine)platinum(II)-benzene(1/1) 
• 137916-10-0 (CO)3Co((C₆H₅)2P)Pt(P(C₆H₅)3)2 

Relevant articles and documents

Capping nido-Nonagermanide Clusters with M-PPh3 and Dynamics in Solution: Synthesis and Structure of closo-[(Me3Si)3Si]3Et[Ge9 M](PPh3) (M = Ni, Pt)

In this work, cluster expansion of nine-atomic germanium clusters with nickel and platinum atoms is reported. The compounds [(Me3Si)3Si]3Et[Ge9Ni](PPh3) and [(Me3Si)3Si]3Et[Ge9Pt](PPh3) are characterized by NMR spectroscopy, elemental analysis, and single crystal X-ray structure analysis. The latter represents the first intermetalloid Ge-Pt cluster with a platinum atom as part of a deltahedron. So far, only one compound of this type has been reported for the homologous Pd. Hence, with these new compounds, metal-coordinated deltahedral Ge9 clusters are now known for the whole triad of group 10 elements. The cluster compounds are accessible by treating [(Me3Si)3Si]3EtGe9 with η2-ethylene-bis-(triphenylphosphine)-nickel(0) and η2-ethylene-bis-(triphenylphosphine)-platinum(0), respectively, in toluene. The crystal structure determination reveals ten-vertex-closo-[Ge9M]-cluster cores (M = Ni, Pt) bearing five exo-bonded ligands. Unlike the nine-vertex-cluster [(Me3Si)3Si]3EtGe9, the penta-functionalized platinum containing cluster compound [(Me3Si)3Si]3Et[Ge9Pt](PPh3) does not show fluctuating behavior in solution over a wide temperature range on the NMR time scale, whereas the [(Me3Si)3Si]3Et[Ge9Ni](PPh3) shows highly dynamic processes in solution at ambient temperature.

Reactions of organotin(IV) compounds with platinum complexes. Part II. Oxidative addition of SnRxCl4-x to [Pt(COD)2] and subsequent reactions with tertiary phosphines

Organotin(IV) compounds SnRxCl4-x (R=Me, Ph; x=4-0) add oxidatively to [Pt(COD)2] (COD=cycloocta-1,5-diene) to yield platinum(II) complexes in which Pt has inserted into the Sn-Cl or Sn-R bonds, displacing one COD entity. The new com

Synthesis, structure and reactivity of N,O-metallacyclic (dicarbonyldiazene) platinum complexes

Reaction of cis-Pt(PR13)2Cl2 (R1 = Me, Ph) with diacyl hydrazine R2OCNHNHCOR2 (R2 = Me, Ph) in refluxing ethanol and NaHCO3 afforded platinum diazene diacyl complexes Pt(PR13)2(R2OCNNCOR2) (1, R1 = R2 = Ph; 3, R1 = Me, R2 = Ph; 4, R1 = R2 = Me). Reaction of Pt(PPh3)2(C2H4) with diazene dicarboxylates R2OCNNCOR2 (R2 = OEt, OPri) resulted in the formation of Pt(PPh3)2(R2OCNNCOR2) (2, R2 = OEt; 5, R2 = OPri). Multinuclear NMR spectroscopy on 1-5 revealed that the dicarbonyl-substituted diazene ligand is coordinated asymmetrically, consistent with a five membered Pt-N-N-C-O ring. Compound 5 crystallises from THF-benzene as the solvate Pt(PPh3)2(PriO2CNNCO 2Pri)·(C6H6)2; its X-ray crystal structure shows that the coordination sphere of platinum is essentially square planar and coplanar with the five membered Pt1-O1-C5-N2-N1 ring. The Pt1-O1 distance is 2.027(4) A and the Pt1-N1 distance is 2.050(5) A. The N1-N2 distance is 1.421(6) A while the N2-C5 and C5-O1 distances are 1.273(7) and 1.314(7) A, respectively. Complexes 1-5 show sensitivity towards chlorinated solvents (CH2Cl2, CHCl3) under photolysis conditions, forming the corresponding cis-platinum bis(phosphine) dichloride complexes; the same products are formed in a slower thermal reaction with 2 and 5. Complexes 2 and 5 react photochemically with ethylene in [2H8]THF yielding Pt(PPh3)2(C2H4) but 1, 3 and 4 are inert. Addition of an excess of dppe ligand to 2 and 5 resulted in the displacement of PPh3 and the formation of Pt(dppe)(EtO2CNNCO2Et) and Pt(dppe)(PriO2CNNCO2Pri) [dppe = 1,2-bis(diphenylphosphino)ethane].

Attempted generation of Cp(CO)2Re(μ-H)Pt(PPh3)2[C(CH 3)=CHCH3] from reaction of Cp(CO)2ReH- with (PPh3)3Pt[(E)-C(CH3)=CHCH3] + produces Cp(CO)2Re(cis-CH3CH=CHCH3)

Previously we proposed Cp(CO)2Re(μ-H)Pt-(PPh3)2[C(CH 3)=CHCH3] (II) as a possible intermediate in the reaction of 2-butyne with Cp(CO)2Re(μ-H)Pt(H)-(PPh3)2 (1) to give Cp(CO)2Re(cis-CH3CH=CHCH3) (cis-2). In an attempt to independently synthesize II, the reaction of K+Cp(CO)2ReH- (3) with (PPh3)3Pt(E)-C(CH3)= CHCH3]+CF3SO3- (cis-4) was studied and conversion to cis-2 was observed, but intermediate II was not detected. The reaction is stereospecific: trans-4 reacted with 3 to produce trans-2. K+Cp(CO)2ReD- (3-d) reacted with trans-Pt[C(CH3)=CH2](CF3SO 3)(PPh3)2 (5) to give Cp(CO)2Re(CH2=CDCH3) (6-d), which demonstrated that 3 is the hydride source in these reactions.

Metallacyclobutarenes from cyclopropanaphthalene: reactions with rhodium(I), platinum(0) and palladium(0)

1H-Cyclopropanaphthalene(V) reacts with chlorotris(triphenylphosphine)rhodium(I) and (ethene)bis(triphenylphosphine)platinum(0) with oxidative insertion of the metal into the three-membered ring ?-bond; rhodia- and platina-2H-cyclobutanaphthalenes r

209. The Coordination Chemistry of 1,2-Bisbenzene with Nickel(II), Palladium(II), Platinum(II), and Platinum(0) and the X-Ray Crystals Structure of benzene)(C2H4)>

The preparation of complexes (M = Ni, Pd, and Pt; X = Cl, Br, and I; 1 = 1,2-bisbenzene), , (alkene = C2H4 and CH2 = CHCN), and is reported.Their 1H- and 31P-NMR spectra were recorded and used for structural assignments.The X-ray crystal structure of was determined.It is shown that the P-Pt-P bond angle in this complex differs significantly from those found in related compounds with monodentate phosphines, and that this difference is likely to be due to intramolecular contacts.

Simple Synthesis of (η2-Ethen)bis(triphenylphosphane)platinum(0)

The title compound 2 is easily accessible through reduction of dichlorobis(triphenylphophane)platinum(II) (1) with sodium tetrahydridoborate in ethanol under ethene pressure or without pressure in methylene chloride/ethanol.No nitrogen atmosphere or purified solvents are necessary.

Synthesis and Reactivity of Platinum-Formaldehyde Complexes

Sodium dihydronaphthylide reduction of (R3=Et3, Pri3, Ph3, Et2Ph, or 1/2Ph2PCH2CH2PPh2) under an ethylene atmosphere gives in quantitative yield as shown by (31)P n.m.r. spectroscopy.Reactions of the ethylene complexes with CO, CH2I2, (CF3)2CO, (CO2Et)2CO, and CH2O are described.Monomeric formaldehyde reacts to give the first platinum-formaldehyde complexes, , decomposition of which produces (n=3 or 4) and a complex tentatively assigned as .