1236162-78-9

Basic information

• Product Name: C₅₈H₅₄I₄Si₂
• Synonyms: C₅₈H₅₄I₄Si₂
• CAS NO: 1236162-78-9
• Molecular Weight: 1314.86
• Mol File: 1236162-78-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₅₈H₅₄I₄Si₂(CAS DataBase Reference)
• NIST Chemistry Reference: C₅₈H₅₄I₄Si₂(1236162-78-9)
• EPA Substance Registry System: C₅₈H₅₄I₄Si₂(1236162-78-9)

Safety Data

• Hazardous Substances Data: 1236162-78-9(Hazardous Substances Data)

Upstream product

• 180785-83-5 C₂₂H₂₂ 
• 2170-08-3 dimethylbis(phenylethynyl)silane 

Downstream Products

• 1236162-81-4 C₄₂H₄₆Si₂ 

Relevant articles and documents

Formation of α-lithio siloles from silylated 1,4-dilithio-1,3- butadienes: Mechanism and applications

A full account of a useful transformation from silylated 1,4-dili-thio-1,3-butadienes to α-lithio siloles is described. These lithio siloles formed by this procedure are general, in terms of substitution patterns and synthetic methods, affording diversified silole derivatives. Notably, some structurally complex molecules, such as bridged bis-silole compounds, have been synthesized easily and successfully by applying our protocol. The structure of the α-lithio silole, which adopts a dimeric fashion through two lithium bridges, was confirmed by X-ray analysis. Furthermore, a possible mechanism of the skeleton rearrangements via E/Z isomerization of 1-silyl-1-lithio alkene and nucleophilic attack on silicon is proposed, and is also proved by experimental investigations. 2010 Wiley-VCH Verlag GmbH Co. KGaA, Weinheim.