125764-09-2

Basic information

• Product Name: tetraethylammonium bis<α,α-bis(trifluoromethyl)benzenemethanolato(2-)-C²,O>cyclohexylsilicate
• Synonyms: tetraethylammonium bis<α,α-bis(trifluoromethyl)benzenemethanolato(2-)-C²,O>cyclohexylsilicate
• CAS NO: 125764-09-2
• Molecular Weight: 725.733
• Mol File: 125764-09-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: tetraethylammonium bis<α,α-bis(trifluoromethyl)benzenemethanolato(2-)-C²,O>cyclohexylsilicate(CAS DataBase Reference)
• NIST Chemistry Reference: tetraethylammonium bis<α,α-bis(trifluoromethyl)benzenemethanolato(2-)-C²,O>cyclohexylsilicate(125764-09-2)
• EPA Substance Registry System: tetraethylammonium bis<α,α-bis(trifluoromethyl)benzenemethanolato(2-)-C²,O>cyclohexylsilicate(125764-09-2)

Safety Data

• Hazardous Substances Data: 125764-09-2(Hazardous Substances Data)

Upstream product

• 108-85-0 1-bromocyclohexane 
• 70091-69-9 3,3,3',3'-tetrakis(trifluoromethyl)-1,1'(3H,3'H)-spirobi<2,1-benzoxasilole> 
• 71-91-0 tetraethylammonium bromide 

Downstream Products

• 56947-80-9 2-cyclohexyl-4-methylquinoline 
• 37597-46-9 4‐cyclohexyl‐2‐methylquinoline 
• 123005-17-4 2,4-dicyclohexylquinoline 
• 106662-18-4 methyl 1-cyclohexylisoquinoline-3-carboxylate 
• 16573-53-8 6‐cyclohexylphenanthridine 
• 40115-03-5 2-cyclohexyl-benzothiazole 
• 26059-80-3 2-cyclohexyl-4-hydroxyquinazoline 
• 107228-60-4 3,6-dichloro-4-cyclohexylpyridazine 
• 46498-49-1 3-Cyclohexyl-3-phenylpropanal 
• 137542-86-0 (3R)-3-cyclohexyl-3-phenylpropanal 

Relevant articles and documents

Terminal-oxidant-free photocatalytic C-H alkylations of heteroarenes with alkylsilicates as alkyl radical precursors

We report the photocatalytic C-H alkylations of heteroarenes with alkylsilicates bearing C,O-bidentate ligands under acidic conditions. Irradiation of heteroaromatics in the presence of the silicates and trifluoroacetic acid produced the corresponding alkylated compounds. The present reaction system does not require any terminal oxidant although the reaction seems to be a formal oxidation reaction. This study demonstrates that alkylsilicates can be used in photocatalytic radical chemistry under acidic conditions.