13153-91-8Relevant articles and documents
Enantioselective deprotonation as a vehicle for the asymmetric synthesis of C2-symmetric P-chiral diphosphines
Muci, Alexander R.,Campos, Kevin R.,Evans, David A.
, p. 9075 - 9076 (2007/10/03)
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Stereospecific Synthesis of Diastereoisomerically Pure (-)-(RP)-O-Mentyl Methylphenylphosphinite and Ethylphenylphosphinite: Key Intermediates in Synthesis of Chiral Tertiary Phosphines
Omelanczuk, Jan,Perlikowska, Wieslawa,Mikolajczyk, Marian
, p. 24 - 25 (2007/10/02)
The reaction of the diastereoisomerically pure (-)-(RP)-O-mentyl methylphenylphosphinite (9) and (-)-(RP)-O-mentyl ethylphenylphosphinite (2) with organolithium reagents has been found to give chiral tertiary phosphines (10) and (11) with a very high optical purity.