(-)-Methylphenylpropylphosphine sulfide

Base Information

• Chemical Name: (-)-Methylphenylpropylphosphine sulfide
• CAS No.: 13153-91-8
• Molecular Formula: C10H15PS
• Molecular Weight: 198.269
• Hs Code.: 2930909090
• Mol file: 13153-91-8.mol

Synonyms:(-)-Methylphenylpropylphosphine sulfide

Chemical Property of (-)-Methylphenylpropylphosphine sulfide

Chemical Property:

• PSA: 41.90000
• LogP: 3.48180

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (-)-Methylphenylpropylphosphine sulfide

There total 7 articles about (-)-Methylphenylpropylphosphine sulfide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(-)-(R)-methyl-n-propylphenylphosphine (701-03-1,4653-62-7,13153-89-4) → (-)-(S)-methyl-n-propylphenylphosphine sulphide (13153-91-8)

Guidance literature:

With sulfur;

DOI:10.1021/ja00518a026

Reference yield:

trifluoromethanesulfonic acid ethyl ester (425-75-2) + dimethylphenylphosphine sulfide (1707-00-2) → (+)-(R)-methyl-n-propylphenylphosphine sulphide (13153-92-9) + (-)-(S)-methyl-n-propylphenylphosphine sulphide (13153-91-8)

Guidance literature:

With n-butyllithium; (-)-sparteine; diethylamine; Multistep reaction. Title compound not separated from byproducts;

DOI:10.1021/ja00140a028

Reference yield:

O-menthyl methylphenylphosphinite → (-)-(S)-methyl-n-propylphenylphosphine sulphide (13153-91-8)

Guidance literature:

Multi-step reaction with 2 steps

1: diethyl ether / Heating

2: S₈

With sulfur; In diethyl ether;

DOI:10.1039/c39800000024

upstream raw materials:

(-)-(R)-methyl-n-propylphenylphosphine

(+)R-methyl-n-propylphenylmethylselenophosphonium triflate

trifluoromethanesulfonic acid ethyl ester

dimethylphenylphosphine sulfide

Downstream raw materials:

(R)-(+)-methylphenyl-n-propylphosphine oxide

(S)-(-)-Methylphenyl-n-propylphosphanoxid

(E)-N-methyl-1-(4-nitrophenyl)methanimine

4-nitrobenzaldehdye

Refernces

• 1、 Omelanczuk, Jan,Mikolajczyk, Marian. "STEREOSPECIFIC INTERCONVERSION OF THIO- AND SELENOPHOSPHORYL COMPOUNDS". . p. 321 - 326. Retrieved 2007/10/02.