133124-42-2Relevant articles and documents
Zirconium-catalyzed reaction of terminal alkenes with triethylindium
Ramazanov,Dil'Mukhametova,Dzhemilev
, p. 1253 - 1256 (2013)
Terminal alkenes (undec-1-ene, oct-1-ene, and allylbenzene) reacted with triethylindium in the presence of a catalytic amount of Cp2ZrCl 2 in hexane to give mixtures of three organoindium compounds whose hydrolysis in D2O afforded 2-substituted 1,4-dideuterobutane containing minor amounts of 2-substituted 1- and 4-deuterobutanes.
Cyclomagnesation of olefins with ethylmagnesium bromide in the presence of titanium complexes
Dzhemilev,D'yakonov,Khafizova,Ibragimov
, p. 352 - 357 (2007/10/03)
Cyclomagnesation of terminal and cyclic olefins and 1,2-dienes with RMgHlg and R2Mg in the presence of dichloro(dicyclopentadienyl)titanium(IV) gives non-Grignard cyclic and acyclic organomagnesium compounds. The reaction direction depends on t