133124-42-2Relevant articles and documents
Zirconium-catalyzed reaction of terminal alkenes with triethylindium
Ramazanov,Dil'Mukhametova,Dzhemilev
, p. 1253 - 1256 (2013)
Terminal alkenes (undec-1-ene, oct-1-ene, and allylbenzene) reacted with triethylindium in the presence of a catalytic amount of Cp2ZrCl 2 in hexane to give mixtures of three organoindium compounds whose hydrolysis in D2O afforded 2-substituted 1,4-dideuterobutane containing minor amounts of 2-substituted 1- and 4-deuterobutanes.
Catalytic enantioselective ethylalumination of terminal alkenes: Substrate effects and absolute configuration assignment
Parfenova, Lyudmila V.,Kovyazin, Pavel V.,Tyumkina, Tatyana V.,Makrushina, Alyona V.,Khalilov, Leonard M.,Dzhemilev, Usein M.
, p. 124 - 135 (2015/02/19)
The chemo- and enantioselectivity of the reaction of alkenes with AlEt3 catalyzed by bis(1-neomenthylindenyl)zirconium dichloride has been studied. The reaction with linear alkenes in a chlorinated solvent (CH2Cl2) gives m
Cyclomagnesation of olefins with ethylmagnesium bromide in the presence of titanium complexes
Dzhemilev,D'yakonov,Khafizova,Ibragimov
, p. 352 - 357 (2007/10/03)
Cyclomagnesation of terminal and cyclic olefins and 1,2-dienes with RMgHlg and R2Mg in the presence of dichloro(dicyclopentadienyl)titanium(IV) gives non-Grignard cyclic and acyclic organomagnesium compounds. The reaction direction depends on t
SYNTHESIS AND TRANSFORMATIONS OF METALLOCYCLES. 5. REGIOSELECTIVE SYNTHESIS OF β-SUBSTITUTED ALUMOCYCLOPENTANES BY THE CYCLOMETALLATION OF α-OLEFINS USING Et3Al IN THE PRESENCE OF Cp2ZrCl2
Dzhemilev, U. M.,Ibragimov, A. G.,Zolotarev, A. P.,Muslukhov, R. R.,Tolstokov, G. A.
, p. 2570 - 2578 (2007/10/02)
A new method has been proposed for the synthesis of N-, O-, and S-containing alumocyclopentanes by the reaction of Et3Al with functional α-olefins in the presence of catalytic amounts of Cp2ZrCl2.The alumocyclopentanes obtained may react with S8 to give β-substituted tetrahydrothiophenes.
