1352656-24-6

Basic information

• Product Name: (E)-ethyl 1-phenylbut-2-enyl carbonate
• Synonyms: (E)-ethyl 1-phenylbut-2-enyl carbonate
• CAS NO: 1352656-24-6
• Molecular Weight: 220.268
• Mol File: 1352656-24-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (E)-ethyl 1-phenylbut-2-enyl carbonate(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-ethyl 1-phenylbut-2-enyl carbonate(1352656-24-6)
• EPA Substance Registry System: (E)-ethyl 1-phenylbut-2-enyl carbonate(1352656-24-6)

Safety Data

• Hazardous Substances Data: 1352656-24-6(Hazardous Substances Data)

Upstream product

• 52755-39-2 (2E)-1-phenylbut-2-en-1-ol 
• 1609-47-8 diethyl dicarbonate 

Downstream Products

• 16939-57-4 (E)-buta-1,3-dienylbenzene 
• 36004-04-3 ethyl (E)-1-phenylbut-1-en-3-ol 
• 7302-00-3 (E)-1,3-diphenyl-1-butene 

Relevant articles and documents

Pd-catalyzed regioselective and stereospecific Suzuki-Miyaura coupling of allylic carbonates with arylboronic acids

The Pd-catalyzed Suzuki-Miyaura coupling reaction of unsymmetric 1,3-disubstituted secondary allylic carbonates with arylboronic acids has been developed in a wet solvent under a base-free system to afford allyl-aryl coupling products in a high level of isolated yields with complete regio- and E/Z-selectivities with good to excellent chemoselectivities. The coupling reaction of optically active allyl carbonates gave allyl-aryl coupling products with excellent enantioselectivities with inversion of the stereochemistry. This coupling method was successfully applied to the synthesis of (S)-naproxen.