1373751-83-7

Basic information

• Product Name: 1-azido-2-tert-butyl-4-methoxybenzene
• Synonyms: 1-azido-2-tert-butyl-4-methoxybenzene
• CAS NO: 1373751-83-7
• Molecular Weight: 205.26
• Mol File: 1373751-83-7.mol

Chemical Properties

• CAS DataBase Reference: 1-azido-2-tert-butyl-4-methoxybenzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-azido-2-tert-butyl-4-methoxybenzene(1373751-83-7)
• EPA Substance Registry System: 1-azido-2-tert-butyl-4-methoxybenzene(1373751-83-7)

Safety Data

• Hazardous Substances Data: 1373751-83-7(Hazardous Substances Data)

Upstream product

• 13780-90-0 N-(2-tert-butyl-4-hydroxy-phenyl)-acetamide 
• 720712-00-5 2-tert-butyl-4-methoxy-phenylamine 
• 24197-41-9 4-hydroxy-2-(tert-butyl)aniline 
• 1190867-66-3 N-(2-tert-butyl-4-methoxy-phenyl)-acetamide 

Downstream Products

• 1914-02-9 3,3-dimethylindoline 
• 87234-77-3 3,3-dimethyl-5-methoxy-indoline 

Relevant articles and documents

Iron-Catalyzed Intramolecular Aminations of C(sp3)?H Bonds in Alkylaryl Azides

The nucleophilic iron complex Bu4N[Fe(CO)3(NO)] (TBA[Fe]) catalyzes the direct intramolecular amination of unactivated C(sp3)?H bonds in alkylaryl azides, which results in the formation of substituted indoline and tetrahydroquinoline derivatives.

Rh2(II)-catalyzed intramolecular aliphatic C-H bond amination reactions using aryl azides as the N-atom source

Rhodium(II) dicarboxylate complexes were discovered to catalyze the intramolecular amination of unactivated primary, secondary, or tertiary aliphatic C-H bonds using aryl azides as the N-atom precursor. While a strong electron-withdrawing group on the nitrogen atom is typically required to achieve this reaction, we found that both electron-rich and electron-poor aryl azides are efficient sources for the metal nitrene reactive intermediate.