139375-92-1

Basic information

• Product Name: (η⁵-2,4-dimethyl-1-oxa-2,4-pentadienyl)(η⁵-1,2,3,4,5-pentamethylcyclopentadienyl)ruthenium
• Synonyms: (η⁵-2,4-dimethyl-1-oxa-2,4-pentadienyl)(η⁵-1,2,3,4,5-pentamethylcyclopentadienyl)ruthenium
• CAS NO: 139375-92-1
• Molecular Weight: 333.436
• Mol File: 139375-92-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (η⁵-2,4-dimethyl-1-oxa-2,4-pentadienyl)(η⁵-1,2,3,4,5-pentamethylcyclopentadienyl)ruthenium(CAS DataBase Reference)
• NIST Chemistry Reference: (η⁵-2,4-dimethyl-1-oxa-2,4-pentadienyl)(η⁵-1,2,3,4,5-pentamethylcyclopentadienyl)ruthenium(139375-92-1)
• EPA Substance Registry System: (η⁵-2,4-dimethyl-1-oxa-2,4-pentadienyl)(η⁵-1,2,3,4,5-pentamethylcyclopentadienyl)ruthenium(139375-92-1)

Safety Data

• Hazardous Substances Data: 139375-92-1(Hazardous Substances Data)

Downstream Products

• 84821-53-4 bis(pentamethylcyclopentadienyl)ruthenium(II) 
• 404914-52-9 [(η5-C5Me5)Ru(exo,syn-η3-CH2C(Me)CHC(Me)O)Cl2] 
• 404914-52-9 [(η5-C5Me5)Ru(endo,anti-η3-CH2C(Me)CHC(Me)O)Cl2] 
• 856384-86-6 [(C5Me5)Ru(1-5-η-CH2C(Me)CHC(CH2C(Me)2CH2C(O))CH)] 

Relevant articles and documents

Syntheses, structures, and reactivity studies of half-open ruthenocenes and their oxodienyl analogues

Improved synthetic routes to Cp*Ru(Pdl) complexes (Pdl = 2,4-dimethylpentadienyl and various oxodienyl ligands) including Cp*Ru(η5-2,4-Me2-C4 H3O) (1), Cp*Ru[η5-2,4-(t-Bu)2-C4 H3O] (1'), and Cp*ru(η5-2,4-Me2-C5 H5) (1″) were developed. When chelating, diphosphines were used as coligands and reactions with O2, Cl2 or H2 led to oxidative addition. A carbon-carbon bond activation was reported.