14006-85-0

Basic information

• Product Name: 3-methyl-4,5,6,7-tetrahydro-1H-indole
• Synonyms: 1H-indole, 4,5,6,7-tetrahydro-3-methyl-; 3-Methyl-4,5,6,7-tetrahydro-1H-indole
• CAS NO: 14006-85-0
• Molecular Formula: C₉H₁₃N
• Molecular Weight: 135.2062
• Mol File: 14006-85-0.mol
• Article Data: 7

Chemical Properties

• Boiling Point: 264.2°C at 760 mmHg
• Flash Point: 106.6°C
• Density: 1.033g/cm³
• Vapor Pressure: 0.0161mmHg at 25°C
• Refractive Index: 1.559
• CAS DataBase Reference: 3-methyl-4,5,6,7-tetrahydro-1H-indole(CAS DataBase Reference)
• NIST Chemistry Reference: 3-methyl-4,5,6,7-tetrahydro-1H-indole(14006-85-0)
• EPA Substance Registry System: 3-methyl-4,5,6,7-tetrahydro-1H-indole(14006-85-0)

Safety Data

• Hazardous Substances Data: 14006-85-0(Hazardous Substances Data)

Upstream product

• 151051-63-7 3-Methyl-4,5,6,7-tetrahydro-1H-indole-2-carboxylic acid 
• 172907-60-7 1-(Dimethylamino)-4,5,6,7-tetrahydro-3-methyl-1H-indole 
• 83-34-1 3-Methylindole 
• 91-17-8 decalin 
• 6651-36-1 1-(Trimethylsilyloxy)cyclohexene 
• 37945-37-2 ethyl 3-methyl-4,5,6,7-tetrahydro-1H-indole-2-carboxylate 
• 53561-17-4 O-allyl ether of cyclohexanone oxime 
• 108-94-1 cyclohexanone 

Relevant articles and documents

STABILIZATION OF ACTIVE METAL CATALYSTS AT METAL-ORGANIC FRAMEWORK NODES FOR HIGHLY EFFICIENT ORGANIC TRANSFORMATIONS

Metal-organic framework (MOFs) compositions based on post?synthetic metalation of secondary building unit (SBU) terminal or bridging OH or OH2 groups with metal precursors or other post-synthetic manipulations are described. The MOFs provide a versatile family of recyclable and reusable single-site solid catalysts for catalyzing a variety of asymmetric organic transformations, including the regioselective boryiation and siiylation of benzyiic C—H bonds, the hydrogenation of aikenes, imines, carbonyls, nitroarenes, and heterocycles, hydroboration, hydrophosphination, and cyclization reactions. The solid catalysts can also be integrated into a flow reactor or a supercritical fluid reactor.

Carbon-carbon bond formation and pyrrole synthesis via the [3,3] sigmatropic rearrangement of O-vinyl oxime ethers

A new method for the synthesis of 2,4- and 2,3,4-substituted pyrroles in two or three steps from commercially available ketones and allyl hydroxylamine is described. An iridium-catalyzed isomerization reaction has been developed to convert O-allyl oximes

New efficient, flexible and regioselective synthesis of 2,4-Di- and 2,3,4-trialkylated and arylated 1H-pyrroles

Starting from easily available 2-acetoxy aldehyde dimethylhydrazones rac-2, we prepared various alkyl- and aryl-substituted 1H-pyrroles 6 in good overall yield. The titanium-mediated a2-umpolung reaction of rac-2 with different acyclic and cyclic silyl enol ethers 3 leads directly or via 4-oxo hydrazones rac,anti-4 to 1-(dimethylamino)-1H-pyrroles 5. A novel method for the reductive removal of the dimethylamino group affording 1H-pyrroles 6 is presented. VCH Verlagsgesellschaft mbH, 1996.