1462-54-0Relevant articles and documents
pH-responsive N-lauryl-(alpha-alkyl)-beta-aminopropanoic acid ampholytic surfactant, and preparation method and applications thereof
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Paragraph 0034, (2018/11/03)
The invention relates to a pH-responsive N-lauryl-(alpha-alkyl)-beta-aminopropanoic acid ampholytic surfactant, and a preparation method and applications thereof. The preparation method comprises following steps: alkylamine and a solvent are introduced into a three-neck flask for stirring and complete dissolving, alpha-alkyl-methyl acrylate is added dropwise slowly, ice water bath is stopped, roomtemperature reaction is carried out, water bath backflow reaction is adopted, rotary evaporation is carried out to remove the solvent and residual alpha-alkyl-methyl acrylate and obtain product N-lauryl-(alpha-alkyl)-beta-aminopropanoic acid, the N-lauryl-(alpha-alkyl)-beta-aminopropanoic acid and water are introduced into a three-neck flask, a sodium hydroxide solution is added dropwise slowly,water bath reaction is carried out so as to obtain a crude product, and filtering drying is carried out so as to obtain purified N-lauryl-(alpha-alkyl)-beta-aminopropanoic acid sodium. The pH-responsive N-lauryl-(alpha-alkyl)-beta-aminopropanoic acid ampholytic surfactant can be used in a foam acid liquid system as an acid liquid surfactant, is sensitive to pH value, opening and closing can be realized at a pH value lower than 7 and a pH value higher than 7, synthesis process is simple, operation is convenient, synthesis of complex switchable surfactants is avoided, and the application value is high.
AMINO AND IMINO PROPIONIC ACIDS, PROCESS OF PREPARATION AND USE
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Paragraph 0055, (2015/04/28)
N-alkyl, N-alkenyl, N-cycloalkyl, N-aryl amino or imino propionic acids with an alkyl chain ranging from 6 to 18 carbons, or alkenyl chain from 8 to 30 carbons, are obtained from a reaction process in the absence of solvent at a temperature range from 30 to 180° C. and a time of 1 to 10 hours at atmospheric pressure. Formulations composed of N-alkyl or N-alkenyl or N-cycloalkyl or N-aryl amino or imino propionic acids, polyethers derived from propylene oxide or ethylene oxide or copolymer thereof and a solvent consisting of aromatic compounds such as toluene or xylene, diesel or gasoline or alcohols such as isopropanol and ethanol, or mixtures thereof, are obtained inhibit ferrous metal corrosion of pipelines and storage tanks and transport crude oil and liquid fuels. A method inhibiting corrosion of ferrous metals adds an effective amount of the corrosion inhibitor to a petroleum based material such as crude oil and liquid fuels such as gasoline, diesel fuel, and aviation fuel.
NMR STUDY OF PRODUCTS OF NUCLEOPHILIC ADDITION OF HIGHER PRIMARY ALIPHATIC AMINES TO ACRYLIC ACID
Mikhalkin, A. P.,Gorshkova, L. V.,Rybalka, I. G.
, p. 1815 - 1816 (2007/10/03)
The structures of products of nucleophilic addition of higher primary aliphatic amines (C12, C18, and C18:1) to acrylic ac id have been studied by 1H and 13C NMR spectroscopy.
Syntheses d'amidoesters par reaction de Kolbe
Abderrahman, Ben Moufida,Laurent, Eliane,Marquet, Bernard
, p. 571 - 578 (2007/10/02)
The synthesis of amidoesters has been investigated by anodic cooxidation of diacid hemiesters CO2H-CH2-Z-CO2CH3 -CH2-> and amidoacids R1-N(Y)-(CH2)2-CO2H .The scope of this reaction was examined in detail.This synthetic pathway provided very a simple access to a wide range of amidoesters R1-N(Y)-(CH2)3-Z-CO2CH3 by varying Z and R1 as well as n value.