14917-14-7

Basic information

• Product Name: Ni(CO)2(2,2'-bipyridine)
• Synonyms: Ni(CO)2(2,2'-bipyridine)
• CAS NO: 14917-14-7
• Molecular Weight: 270.898
• Mol File: 14917-14-7.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Ni(CO)2(2,2'-bipyridine)(CAS DataBase Reference)
• NIST Chemistry Reference: Ni(CO)2(2,2'-bipyridine)(14917-14-7)
• EPA Substance Registry System: Ni(CO)2(2,2'-bipyridine)(14917-14-7)

Safety Data

• Hazardous Substances Data: 14917-14-7(Hazardous Substances Data)

Upstream product

• 72918-77-5 Ni(C₂H₅)(OC₆H₄CN)(C₁₀H₈N₂) 
• 72918-80-0 Ni(CH₃)(OC₆H₅)(C₁₀H₈N₂) 
• 366-18-7 [2,2]bipyridinyl 
• 13463-39-3 tetracarbonyl nickel 
• 1295-35-8 bis(1,5-cyclooctadiene)nickel ⁽⁰⁾ 
• 637-27-4 phenyl propionate 
• 55425-72-4 (2,2'-bipyridyl)(1,5-cyclooctadiene)nickel 
• 15218-76-5 diethyl(2,2'-bipyridyl)nickel(II) 
• 72918-78-6 NiCH₃(OC₆H₄CN)((C₅H₄N)2) 
• 72930-43-9 Ni(COC₂H₅)(OC₆H₄CN)(C₁₀H₈N₂) 
• 72918-83-3 Ni(COCH₃)(OC₆H₄CN)(C₁₀H₈N₂) 

Downstream Products

• 13463-39-3 tetracarbonyl nickel 
• 80973-99-5 (C₅H₄N)2Ni(CO)2(C₆H₅CCH) 
• 79121-09-8 C₂₇H₁₈N₂NiO₃ 

Relevant articles and documents

Metallocomplexes, exhibiting catecholate binding mode for o-quinone, annulated with dithiete cycle

Novel catecholate complexes (ditCat)SbPh3 (1), (ditCat)Ni(2,2′-bpy) (2) and (3,6-tBu-ditCat)VCp2 (3), containing annulated dithiete cycle, were synthesized by reactions of bifunctional o-quinone, annulated with dithiete ring (ditQ) w

Reductive elimination of aryl carboxylates from acyl(aryloxy)nickel(II) and -palladium(II) complexes

Acyl(p-cyanophenoxy)nickel(II) and -palladium(II) complexes, M(COR)(OC6H4-p-CN)L2 (M = Ni, Pd; L2 = bpy, (PEt3)2), have been prepared by insertion reactions of CO into the metal-carbon bonds of the corresponding methylnickel(II) and -palladium(II) complexes. Addition of π-acids such as CO, maleic anhydride, and acrylonitrile selectively induces reductive elimination of p-cyanophenyl acetate from acylnickel(II) complexes, whereas thermolysis of the complexes mainly results in decarbonylation. In contrast, reductive elimination from the palladium analogue proceeds smoothly on thermolysis, and no apparent accelerating effect of added π-acids is observed. Kinetic studies of both reductive eliminations reveal that the former proceeds via an associative mechanism involving a five-coordinate intermediate, whereas the latter proceeds via two mechanisms, one being a dissociative pathway involving a three-coordinate species and the other being a direct reductive elimination from a four-coordinate species.

Insertion of Carbon Monoxide into Nickel-Alkyl Bonds of Monoalkyl- and Dialkylnickel(II) Complexes, NiR(Y)L2 and NiR2L2. Preparation of Ni(COR)(Y)L2 from NiR(Y)L2 and Selective Formation of Ketone, Diketone, and Aldehyde from NiR2L2

Reactions of monoalkylnickel(II) complexes, NiR(Y)L2 (R=CH3, C2H5; Y=Cl, suc(succinimido), pht(phthalimido), OC6H4-p-CN; L=1/2 bpy (2,2'-bipyridine), PEt3 (triethylphosphine)), with CO afford monoacylnickel(II) complexes, Ni(COR)(Y)L2, which are characterized by elemental analysis and spectroscopies (IR and NMR).Reactions of the acylnickel(II) complexes with alcohols and aniline give the corresponding esters and amides, respectively.Exposure of Ni(COR)(Y)L2 to dry air leads to oxidation of RCO to a RCOO ligand giving a complex formulated as NI(OCOR)(Y)L2.Reactions of dimethylnickel(II) complexes, Ni(CH3)2L2 (L=1/2 bpy, PEt3, 1/2dpe (1,2-bis(diphenylphosphino)ethane, 1/2 dpp (1,3-bis(diphenylphosphino)propane), with carbon monoxide afford acetone and/or 2,3-butanedione in medium to high yields, the acetone/2,3-butanedione ratio varying with the ligand L, reaction temperature, and additives such as maleic anhydride and triphenylphosphine.Generally the acetone/2,3-butanedione ratio decreases with increase in thermal stabilities of Ni(CH3)2L2.Ni(C2H5)2(bpy) and Ni(n-C3H7)2(bpy) give 3-pentanone and 4-heptanone, respectively, on treating them with CO, whereas Ni(C2H5)2(dpe) produces C2H5CHO and C2H4.