Ni(CO)2(2,2'-bipyridine)

Base Information

• Chemical Name: Ni(CO)2(2,2'-bipyridine)
• CAS No.: 14917-14-7
• Molecular Formula: C₁₂H₈N₂NiO₂
• Molecular Weight: 270.898
• Mol file: 14917-14-7.mol

Synonyms:Ni(CO)2(2,2'-bipyridine)

Chemical Property of Ni(CO)2(2,2'-bipyridine)

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Ni(CO)2(2,2'-bipyridine)

There total 16 articles about Ni(CO)2(2,2'-bipyridine) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

Ni(CH3)(OC6H5)(C10H8N2) (72918-80-0) → Ni(CO)2(2,2'-bipyridine) (14917-14-7) + Phenyl acetate (122-79-2,34474-31-2)

Guidance literature:

With carbon monoxide; In tetrahydrofuran; (N2 or Ar), complex dissolved in THF, evacuated, excess CO introduced at room temp.C for 0.3 h; IR;

DOI:10.1021/om00125a033

Reference yield: 89.0%

dimethyl(2,2'-bipyridyl)nickel(II) → Ni(CO)2(2,2'-bipyridine) (14917-14-7) + acetaldehyde (75-07-0,9002-91-9) + dimethylglyoxal (431-03-8) + acetone (67-64-1)

Guidance literature:

With carbon monoxide; In diethyl ether; byproducts: 2,2'-bipyridyl; Et2O soln. of Ni complex stirred under CO at -78°C for 1 d, warmed to room temp.; drying up; GLC anal.;

DOI:10.1246/bcsj.54.2161

Reference yield: 80.0%

Ni(C2H5)(OC6H4CN)(C10H8N2) (72918-77-5) → Ni(CO)2(2,2'-bipyridine) (14917-14-7) + propionic acid 4-cyanophenyl ester (70978-62-0)

Guidance literature:

With carbon monoxide; In tetrahydrofuran; (N2 or Ar), complex dissolved in THF, evacuated, excess CO introduced at room temp. for 1 h; IR;

DOI:10.1021/om00125a033

upstream raw materials:

Ni(C₂H₅)(OC₆H₄CN)(C₁₀H₈N₂)

Ni(COCH₃)(OC₆H₄CN)(C₁₀H₈N₂)

Ni(COC₂H₅)(OC₆H₄CN)(C₁₀H₈N₂)

NiCH₃(OC₆H₄CN)((C₅H₄N)2)

Downstream raw materials:

tetracarbonyl nickel

C₂₇H₁₈N₂NiO₃

(C₅H₄N)2Ni(CO)2(C₆H₅CCH)