15323-21-4Relevant articles and documents
Carbenadibenzocycloheptane: Steady-state and time-resolved spectroscopic laser studies
Doss,Abdel-Wahab,Fruehof,Duerr,Gould,Turro
, p. 434 - 438 (2007/10/02)
A Hammett study of the reactions of carbenadibenzocycloheptane with para-substituted styrenes indicates that this carbene adds to the styrenes as a weak ambiphile. Evidence is obtained that reaction from both singlet and triplet states of this carbene can
THE IRON CARBONYL INDUCED DEOXYGENATION OF ALCOHOLS
Alper, Howard,Salisova, Marta
, p. 801 - 804 (2007/10/02)
Alcohols, able to form stable carbanions, are deoxygenated to hydrocarbons by treatment with potassium, iron pentacarbonyl, and then hydrochloric acid.Use of an alkyl halide in place of HCl results in reductive alkylation.