15780-28-6Relevant articles and documents
Nascent rotational quantum state distribution of NaH (NaD) from the reaction of Na*(42P) with H2, D2, and HD
Bililign, Solomon,Kleiber, P. D.
, p. 213 - 217 (1992)
The nascent rotational quantum state distributions of NaH and NaD products resulting from the reactions of Na*(42Pj) with H2, D2, and HD have been determined using the laser pump-probe technique.We have observed a bimodal rotational distribution with a minor component peaking at low J and a major component peaking at high J.We have observed no evidence for a kinematic isotope effect on the product distribution.Our results are consisent with a model wherein the reaction occurs predominantly on the attractive 2B2 potential energy surface in near C2v geometry with the rotational distribution being determined late in the exit channel.
Hydrogen diffusion in NaH as derived from isotope exchange experiments
Borgschulte,Pendolino,Gremaud,Zuettel
, (2009)
We report on hydrogen-deuterium-exchange experiments on NaH probed by thermogravimetry. From the measurements a diffusion parameter of deuterium in NaH of D=1.1× 10-17 m2 /s at 523 K is derived. The activation energy of tracer diffus
Spectroscopy of the NaH, NaD, KH, and KD X 1Σ+ ground state by laser excited fluorescence in a high frequency discharge
Giroud, Marc,Nedelec, O.
, p. 4151 - 4155 (2007/10/02)
By laser excited fluorescence of the hydrides obtained in a discharge, the ground state vibrational levels of NaH, NaD, KH, and KD, have been observed up to v = 15, 20, 14, and 16, respectively , instead of v = 8,2 , 4, and 4 by conventional spectroskopy.Experimental values of Gv , Bv , and Dv are obtained.Spectroscopic parameters and RKR potential curves are calculated.In NaH and NaD, a comparison can be made with ab initio calculations.
