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L-ISOLEUCINE-TERT-BUTYL ESTER DIBENZENE& is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 16874-08-1 Structure
  • Basic information

    1. Product Name: L-ISOLEUCINE-TERT-BUTYL ESTER DIBENZENE&
    2. Synonyms: L-ISOLEUCINE-TERT-BUTYL ESTER DIBENZENE&;tert-butyl L-isoleucinate;L-Isoleucine tert-butyl ester dibenzenesulfonimide salt;Isoleucine tert-butyl ester;L-Isoleucine 1,1-dimethylethyl ester;Einecs 240-901-8;DRWKBZREIMLHDX-YUMQZZPRSA-N
    3. CAS NO:16874-08-1
    4. Molecular Formula: C10H21NO2
    5. Molecular Weight: 187.27924
    6. EINECS: 240-901-8
    7. Product Categories: N/A
    8. Mol File: 16874-08-1.mol
  • Chemical Properties

    1. Melting Point: 134-135 °C
    2. Boiling Point: 222.4°Cat760mmHg
    3. Flash Point: 90.3°C
    4. Appearance: /
    5. Density: 0.929g/cm3
    6. Vapor Pressure: 0.102mmHg at 25°C
    7. Refractive Index: 1.444
    8. Storage Temp.: N/A
    9. Solubility: N/A
    10. PKA: 7.94±0.39(Predicted)
    11. CAS DataBase Reference: L-ISOLEUCINE-TERT-BUTYL ESTER DIBENZENE&(CAS DataBase Reference)
    12. NIST Chemistry Reference: L-ISOLEUCINE-TERT-BUTYL ESTER DIBENZENE&(16874-08-1)
    13. EPA Substance Registry System: L-ISOLEUCINE-TERT-BUTYL ESTER DIBENZENE&(16874-08-1)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 16874-08-1(Hazardous Substances Data)

16874-08-1 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 16874-08-1 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,6,8,7 and 4 respectively; the second part has 2 digits, 0 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 16874-08:
(7*1)+(6*6)+(5*8)+(4*7)+(3*4)+(2*0)+(1*8)=131
131 % 10 = 1
So 16874-08-1 is a valid CAS Registry Number.
InChI:InChI=1/C10H21NO2/c1-6-7(2)8(11)9(12)13-10(3,4)5/h7-8H,6,11H2,1-5H3

16874-08-1SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name L-Ile-OBu-t

1.2 Other means of identification

Product number -
Other names L-ISOLEUCINE-TERT-BUTYL ESTER DIBENZENE SULFIMIDE SALT

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:16874-08-1 SDS

16874-08-1Relevant articles and documents

Overcoming the Deallylation Problem: Palladium(II)-Catalyzed Chemo-, Regio-, and Stereoselective Allylic Oxidation of Aryl Allyl Ether, Amine, and Amino Acids

Begam, Hasina Mamataj,Jana, Ranjan,Manna, Kartic,Samanta, Krishanu

supporting information, p. 7443 - 7449 (2020/10/09)

We report herein a Pd(II)/bis-sulfoxide-catalyzed intramolecular allylic C-H acetoxylation of aryl allyl ether, amine, and amino acids with the retention of a labile allyl moiety. Mechanistically, the reaction proceeds through a distinct double-bond isomerization from the allylic to the vinylic position followed by intramolecular carboxypalladation and the β-hydride elimination pathway. For the first time, C-H oxidation of N-allyl-protected amino acids to furnish five-membered heterocycles through 1,3-syn-addition is established with excellent diastereoselectivity.

Total synthesis of micromide: A marine natural product

Han, Jianrong,Lian, Jingtang,Tian, Xia,Zhou, Shengwei,Zhen, Xiaoli,Liu, Shouxin

, p. 7232 - 7238 (2015/02/19)

This paper describes an efficient procedure for the synthesis of micromide, a natural product that shows anti-solid-tumor activity. Our strategy involved the synthesis of N-nosyl-protected amino acids and their N-methylation with iodo-methane. The hindered oligopeptides containing N-methyl amino acids were synthesized in excellent yields and high purities.[ampi]]

Pyrrolinone-pyrrolidine oligomers as universal peptidomimetics

Raghuraman, Arjun,Ko, Eunhwa,Perez, Lisa M.,Ioerger, Thomas R.,Burgess, Kevin

supporting information; experimental part, p. 12350 - 12353 (2011/10/02)

Peptidomimetics 1-3 were prepared from amino acid-derived tetramic acids 7 as the key starting materials. Calculations show that preferred conformations of 1 can align their side-chain vectors with amino acids in common secondary structures more effectively than conformations of 3. A good fit was found for a preferred conformation of 2 (an extended derivative of 1) with a sheet/β-turn/sheet motif.

HIV protease inhibiting compounds

-

Page/Page column 91, (2011/01/12)

A compound of the formula is disclosed as an HIV protease inhibitor. Methods and compositions for inhibiting an HIV infection are also disclosed.

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