17118-70-6

Basic information

• Product Name: 2-Phenyl-3-oxoacrylic acid chloride
• Synonyms: 2-Phenyl-3-oxoacrylic acid chloride;Phenyl(chlorocarbonyl)ketene;Phenyl(chloroformyl)ketene;(Chlorocarbonyl)phenylketene
• CAS NO: 17118-70-6
• Molecular Formula: C₉H₅ClO₂
• Molecular Weight: 180.59
• Mol File: 17118-70-6.mol

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2-Phenyl-3-oxoacrylic acid chloride(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Phenyl-3-oxoacrylic acid chloride(17118-70-6)
• EPA Substance Registry System: 2-Phenyl-3-oxoacrylic acid chloride(17118-70-6)

Safety Data

• Hazardous Substances Data: 17118-70-6(Hazardous Substances Data)

Upstream product

• 2613-89-0 phenylmalonic acid 
• 41393-81-1 chlorocarbonyl-phenyl-acetic acid 

Downstream Products

• 55712-14-6 2-(4-chloro-phenyl)-4,6-dioxo-3,5-diphenyl-5,6-dihydro-4H-[1,3]thiazinium betaine 
• 55712-19-1 3-methyl-2-(N-methyl-anilino)-4,6-dioxo-5-phenyl-5,6-dihydro-4H-[1,3]thiazinium betaine 
• 55712-18-0 2-(N-methyl-anilino)-4,6-dioxo-3,5-diphenyl-5,6-dihydro-4H-[1,3]thiazinium betaine 
• 120697-31-6 2,2-tetramethylene-5-oxo-4-phenyl-2,5-dihydroisoxazol-2-ium-3-olate 
• 75526-82-8 anhydro-1-hydroxy-3-oxo-2-phenylpyrazolo<1,2-a>pyrazolium hydroxide 
• 91994-35-3 anhydro-1-hydroxy-7-methyl-3-oxo-2-phenylpyrrolo<1,2-a>imidazolium hydroxide 
• 81685-04-3 7,8-Dihydro-2-oxo-3-phenyl-2H,6H-pyrrolo<2,1-b><1,3>oxazin-5-ium-4-olat 
• 68823-24-5 2-Oxo-3-phenyl-2H-pyrido<2,1-b><1,3>oxazin-5-ium-4-olat 
• 73384-45-9 2-Hydroxy-4-oxo-3-phenyl-4H-imidazo<2,1-b><1,3>thiazine 
• 91994-41-1 anhydro-1-hydroxy-3-oxo-2-phenylpyrrolo<1,2-a>pyridinium hydroxide 
• 81685-05-4 6,7,8,9-Tetrahydro-2-oxo-3-phenyl-2H-pyrido<2,1-b><1,3>oxazin-5-ium-4-olat 
• 128118-63-8 6-chloro-4-oxo-5-phenyl-2-pyrrolidino-4H-1,3-oxazine 
• 68823-05-2 2,3-Dimethyl-6-oxo-5-phenyl-6H-1,3-oxazin-3-ium-4-olat 
• 114505-99-6 anhydro-1-hydroxy-3-oxo2-phenylpyrrolo<2,1-b>benzothiazolium hydroxide 

Relevant articles and documents

Facile 1,3-shift of chlorine in a chlorocarbonylketene

Chlorocarbonyl(phenyl)ketene (2) undergoes a degenerate 1,3-shift of chlorine, as determined by 13C NMR spectroscopy. The two carbonyl signals (183 and 157 ppm) coalesce at -30°C, and from this as well as line-shape analysis, an activation barr

Preparation of arylpropynamides and their reaction with malonyl acid derivatives

Synthesis of arylpropynamides and their reactions with different malonic acid derivatives is described. Treatment of arylpropynamides with unsubstituted malonyl chloride furnished N-(3-arylprop-2-ynoyl)-6-chloro-4-hydroxy-2-oxo-2H- pyran-3-carboxamides; m

A one pot synthesis of 5-phenyl-1,3-dioxane-4,6-dione derivatives

A general procedure for synthesis of 5-phenyl-1,3-dioxane-4,6-dione derivatives is described. The synthesis involves the cycloaddition of (α- chlorocarbonyl)phenylketene with carbonyl compounds to generate the corresponding substituted 2-oxetanone's which is readily transformed to the final products in one step. The 1,3-dioxane-4,6-dione is a rigid cyclic structure, and can undergo easy hydrolysis.

Mesoionic Six-Membered Heterocycles, V. Reactions of 6-Oxo-6H-1,3-oxazin-3-ium-4-olates with o-Quinones and Heterocumulenes

Mesoionic 6-oxo-6H-1,3-oxazine-3-ium-4-olates (1, 7) react with o-quinones (2, 4) to give compounds 3, 5, which may result from a primary cycloaddition and subsequent loss of carbon dioxide.Phenyl isocyanate and phenylisothiocyanate react with 1h and