17355-78-1Relevant articles and documents
Synthesis of 1,2,4-Triazol-3-imines via Selective Stepwise Cycloaddition of Nitrile Imines with Organo-cyanamides
Sharma, Pallavi,Bhat, Shreesha V.,Prabhath, M. R. Ranga,Molino, Andrew,Nauha, Elisa,Wilson, David J. D.,Moses, John E.
supporting information, p. 4263 - 4266 (2018/07/29)
A convenient method for the synthesis of 1,2,4-triazol-3-imines through a selective, formal, 1,3-dipolar cycloaddition of organo-cyanamide ions with nitrile imine dipoles is reported. Hydrolysis of the 1,2,4-triazol-3-imines yields the corresponding 1,2,4-triazol-5-ones. A stepwise mechanism, supported by DFT calculations, is invoked to explain the reaction selectivity.
Novel process for synthesis of 1,2,4-triazoles: Ytterbium triflate-catalyzed cyclization of hydrazonyl chlorides with nitriles
Su, Weike,Yang, Dianwen,Li, Jianjun
, p. 1435 - 1440 (2007/10/03)
A series of 1,3,5-trisubstituted 1,2,4-triazoles were synthesized via the intermolecular cyclization of hydrazonyl chlorides with nitriles catalyzed by ytterbium triflate [Yb(OTf)3]. The amount of catalysis was discussed and Yb(OTf)3 could be reused without loss of activity. Copyright Taylor & Francis, Inc.
NOUVELLE VOIE DE SYNTHESE D'ARYLPYRAZOLO - - QUINOLEINES VIA LA CYCLOADDITION DIPOLAIRE -1,3
Daou, Boujemaa,Soufiaoui, Mohamed
, p. 3351 - 3362 (2007/10/02)
The regiospecificity of the diarylnitrilimines (D.A.N.I) action on the heterocycles such as the benzofuranne and N-methylindole has been demonstrated spectroscopically and chemically.With the N-alkylindoles having an alkoxycarbonyle function in the positi