2050-54-6

Basic information

• Product Name: DIBUTYLCYANAMIDE
• Synonyms: N,N-Dibutyl cyanamide;N-CYANODIBUTYLAMINE;CYANODIBUTYLAMINE;DIBUTYLCYANAMIDE;DIBUTYLAMINE-N-CARBONITRILE;dibutyl-cyanamid;Di-n-butylcyanamide
• CAS NO: 2050-54-6
• Molecular Formula: C₉H₁₈N₂
• Molecular Weight: 154.25
• Product Categories: Aromatic Nitriles
• Mol File: 2050-54-6.mol
• Article Data: 13

Chemical Properties

• Boiling Point: 54-56°C 2mm
• Flash Point: 100.7 °C
• Appearance: /
• Density: 0.8893 (rough estimate)
• Vapor Pressure: 0.00965mmHg at 25°C
• Refractive Index: 1.6210 (estimate)
• Storage Temp.: Sealed in dry,Room Temperature
• CAS DataBase Reference: DIBUTYLCYANAMIDE(CAS DataBase Reference)
• NIST Chemistry Reference: DIBUTYLCYANAMIDE(2050-54-6)
• EPA Substance Registry System: DIBUTYLCYANAMIDE(2050-54-6)

Safety Data

• Hazard Codes: Xi
• Statements: 23/24/25
• Safety Statements: 26-36/37/39
• RIDADR: 2810
• Hazardous Substances Data: 2050-54-6(Hazardous Substances Data)

Usage

General Description

DIBUTYLCYANAMIDE is a chemical compound that is also known as N,N-dibutylcyanamide. Its chemical structure consists of a cyanamide group attached to two butyl groups. It is a colorless to light yellow liquid with a strong ammonia-like odor. DIBUTYLCYANAMIDE has a variety of industrial uses, including as a chemical intermediate in the production of pharmaceuticals, plastics, and agrochemicals. It is also used as a curing agent in the manufacturing of epoxy resins. Additionally, it can be used as a reagent in organic synthesis to facilitate the formation of carbon-carbon and carbon-nitrogen bonds. However, it is important to handle DIBUTYLCYANAMIDE with care, as it is flammable and can cause irritation to the skin, eyes, and respiratory system.

InChI:InChI=1/C9H18N2/c1-3-5-7-11(9-10)8-6-4-2/h3-8H2,1-2H3

Upstream product

• 151-50-8 potassium cyanide 
• 111-92-2 dibutylamine 
• 542-90-5 ethyl isothiocyanate 
• 143-33-9 sodium cyanide 
• 102-82-9 tributyl-amine 
• 172876-96-9 3-oxo-1λ³-benzo[d][1,2]iodaoxole-1(3H)-carbonitrile 
• 7677-24-9 trimethylsilyl cyanide 
• 94665-56-2 N,N-dibutyl-2,2,2-trichloroacetimidamide 
• 506-77-4 cyanogen chloride 
• 35700-30-2 1,1-dibutyl thiourea 
• 619-37-4 N,N-di-n-butylurea 
• 65267-17-6 C₁₂H₂₈N₃⁽¹⁺⁾*I^(1-) 
• 109-69-3 n-Butyl chloride 
• 420-04-2 CYANAMID 

Downstream Products

• 76098-45-8 C₁₉H₂₃ClN₂O₂ 
• 52999-36-7 C₁₅H₂₃Cl₂N₃O₃S₂ 
• 93795-52-9 6-(4-Bromo-phenyl)-2-dibutylamino-[1,3]oxazin-4-one 
• 93795-51-8 6-(4-Chloro-phenyl)-2-dibutylamino-[1,3]oxazin-4-one 
• 84375-28-0 2-Dibutylamino-6-phenyl-[1,3]oxazin-4-one 
• 96977-51-4 2-dibutylamino-5-phenyl-oxazol-4-one 
• 29044-29-9 1.1-Di-n-butyl-2-hydroxyguanidin 
• 111-92-2 dibutylamine 
• 13194-58-6 N,N-Dibutyl-O-methyl-isoharnstoff 

Relevant articles and documents

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N-Cyanation of Primary and Secondary Amines with Cyanobenzio-doxolone (CBX) Reagent

An efficient electrophilic N-cyanation of amines with a stable and less-toxic cyanobenziodoxole reagent towards the synthesis of cyanamides is disclosed. This synthetically practicable strategy allows the construction of a wide variety of cyanamides under very mild and simple conditions with a broad functional group compatibility, and showcases a huge potential in late-stage modification of complex molecules.

Electrochemical strategies for: N -cyanation of secondary amines and α C -cyanation of tertiary amines under transition metal-free conditions

Transition metal-free electrochemical approaches for the N-cyanation of secondary amines and the α C-cyanation of tertiary amines have been well established, with products being obtained in moderate to good yields and with good functional group tolerance under ambient conditions. The synthetic application of the protocols has been highlighted through scale-up experiments in a galvanostatic mode. Preliminary mechanistic investigation has confirmed that TBAB played a critical role in N-cyanation transformation and has indicated that the transformation might proceed via a free radical process. This journal is