26265-69-0Relevant articles and documents
Thermodynamic of the acid-base properties of ethylenediamine in the binary water - dimethylsulphoxide solvent
Nishchenkov, A. V.,Sharnin, V. A.,Shormanov, V. A.,Krestov, G. A.
, p. 134 - 137 (2007/10/02)
The enthalpies of the acid dissociation reactions of the ethylenediammonium ions in a mixed water - dimethylsulphoxide solvent at 298.15 K have been determined calorimetrically.The thermodynamic characteristics of the reactions have been calculated by using previous results.The effect of the water - dimethylsulphoxide solvent on the enthalpic characteristics of the solvation of the reactants and the contributions of these characteristics of the ΔH0 of the acid dissociation reaction have been analysed.
