2674-04-6Relevant articles and documents
Aryl C-N bond formation by electrophilic amination of diarylcadmium reagents with O-substituted ketoximes
Da?kapan, Tahir,Korkmaz, Adem
supporting information, p. 813 - 817 (2016/07/06)
Diorganocadmium reagents cannot react with ketoxime at room temperature. CuCN catalysis allows diarylcadmium reagents to react with ketoxime and to give corresponding arylamines in good to high yields at room temperature. According to the electronic effects of the substituent attached to the aromatic ring, functionalized diarylcadmium reagents show meta-para selectivity in their amination reactions. Also compared to diarylzinc reagents, diarylcadmium reagents react with O-substituted ketoxime under milder reaction conditions and they form corresponding arylamines in higher yields. CuCN cannot help dialkyl-, dicycloalky-, and dibenzylcadmium reagents to react with ketoxime. Our Aryl C-N bond formation method does not include cadmium excretion into the environment.
Reactions of diorganocadmium compounds with other dialkylmetal compounds and macrocycles: Synthesis of organocadmate anions
Tang, Hui,Richey Jr., Herman G.
, p. 1569 - 1574 (2008/10/08)
Combining R2Cd (R an alkyl or Ph group), the corresponding R2Mg compound, and 1,4,8,11-tetramethyl-1,4,8,11-tetraazatetradecane, 2,1,1-cryptand, or 2,2,1-cryptand in solution quantitatively produces R3Cd-1 and R