282540-56-1

Basic information

• Product Name: ethyl 4-O-benzoyl-2,3-O-ethoxyethylidene-1-thio-α-L-rhamnopyranoside
• Synonyms: ethyl 4-O-benzoyl-2,3-O-ethoxyethylidene-1-thio-α-L-rhamnopyranoside
• CAS NO: 282540-56-1
• Molecular Weight: 382.478
• Mol File: 282540-56-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: ethyl 4-O-benzoyl-2,3-O-ethoxyethylidene-1-thio-α-L-rhamnopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl 4-O-benzoyl-2,3-O-ethoxyethylidene-1-thio-α-L-rhamnopyranoside(282540-56-1)
• EPA Substance Registry System: ethyl 4-O-benzoyl-2,3-O-ethoxyethylidene-1-thio-α-L-rhamnopyranoside(282540-56-1)

Safety Data

• Hazardous Substances Data: 282540-56-1(Hazardous Substances Data)

Upstream product

• 78-39-7 Triethyl orthoacetate 
• 145836-02-8 ethyl 4-O-benzoyl-2,3-O-isopropylidene-1-thio-α-L-rhamnopyranoside 
• 145836-03-9 ethyl 4-O-benzoyl-1-thio-α-L-rhamnopyranoside 
• 98-88-4 benzoyl chloride 
• 127753-95-1 ethyl 2,3-O-isopropylidene-1-thio-α-L-rhamnopyranoside 

Relevant articles and documents

Stereoselective synthesis of 2-S-ethyl(phenyl)-2-thio-β-glucopyranosides via 1,2-migration and concurrent glycosidation of ethyl(phenyl) 2,3-orthoester-1-thio-α-mannopyranosides

1,2-Migration and concurrent glycosidation of ethyl(phenyl) 2,3-orthoester-1-thio-α-D- and L-mannopyranosides under the action of TMSOTf readily afforded the corresponding 2-S-ethyl(phenyl)-2-thio-β-glucopyranosides, ready precursors to 2-deoxy-arabino-hexopyranosides (2-deoxy-β-glucopyranosides).