29778-23-2Relevant articles and documents
Efficient copper-catalyzed sonogashira couplings of aryl halides with terminal alkynes in water
Yang, Daoshan,Li, Bing,Yang, Haijun,Fu, Hua,Hu, Liming
scheme or table, p. 702 - 706 (2011/04/26)
An efficient copper-catalyzed method has been developed for Sonogashira couplings of aryl halides with terminal alkynes in water. The protocol uses inexpensive CuBr as the catalyst, 1,10-phenanthroline as the ligand, tetrabutylammonium bromide (TBAB) as the phase-transfer catalyst, environmentally friendly water as the solvent, and various internal alkynes were synthesized in good to excellent yields. Georg Thieme Verlag Stuttgart - New York.
NEW SIMPLE METHOD FOR THE SYNTHESIS OF CIS-STILBENES
Merkushev, E. B.,Skorokhodova, T. S.
, p. 308 - 311 (2007/10/02)
A new method involving catalytic acetylenic condensation as the key stage was developed for the synthesis of cis-stilbenes.Subsequent selective hydrogenation of the synthesized alkyltolanes over Pd-CaCO3 gave a series of alkyl-substituted stilbenes. 1,8-Dimethylphenanthrene was obtained from o-iodotoluene.