3007-73-6

Basic information

• Product Name: N-decylaniline
• Synonyms: N-Decylaniline
• CAS NO: 3007-73-6
• Molecular Formula: C₁₆H₂₇N
• Molecular Weight: 233.3923
• Mol File: 3007-73-6.mol
• Article Data: 23

Chemical Properties

• Boiling Point: 342.5°C at 760 mmHg
• Flash Point: 162.1°C
• Density: 0.906g/cm³
• Vapor Pressure: 7.5E-05mmHg at 25°C
• Refractive Index: 1.514
• PKA: 5.06±0.50(Predicted)
• CAS DataBase Reference: N-decylaniline(CAS DataBase Reference)
• NIST Chemistry Reference: N-decylaniline(3007-73-6)
• EPA Substance Registry System: N-decylaniline(3007-73-6)

Safety Data

• Hazardous Substances Data: 3007-73-6(Hazardous Substances Data)

Upstream product

• 112-31-2 caprinaldehyde 
• 62-53-3 aniline 
• 98-95-3 nitrobenzene 
• 2016-57-1 1-aminodecane 
• 108-90-7 chlorobenzene 
• 764-93-2 1-decyne 
• 112-13-0 n-decanoyl chloride 
• 15473-32-2 decananilide 
• 41233-29-8 methanesulfonic acid decyl ester 
• 112-29-8 1-bromo dodecane 
• 103-70-8 Formanilid 
• 112-30-1 1-Decanol 

Downstream Products

• 1311478-34-8 C₄₀H₆₆N₄O₂ 
• 55239-88-8 C₁₇H₂₆ClNO 

Relevant articles and documents

Switchable Imine and Amine Synthesis Catalyzed by a Well-Defined Cobalt Complex

Switchable imine and amine synthesis catalyzed by a tripodal ligand-supported well-defined cobalt complex is presented herein. A large variety of primary alcohols and amines were selectively converted to imines or amines in good to excellent yields. It is discovered that the base plays a crucial role on the selectivity. A catalytic amount of base leads to the imine formation, while an excess loading of base results in the amine product. This strategy on product selectivity also strongly depends on the organometallic catalysts in use. We expect that the present study could provide useful insights toward selective organic synthesis and catalyst design.

Simple reversible fixation of a magnetic catalyst in a continuous flow system: Ultrafast reduction of nitroarenes and subsequent reductive amination using ammonia borane

Continuous reductive amination of aldehydes with nitroarenes over a Pd-Pt-Fe3O4 catalyst was performed. We used NH3BH3 as not only a hydrogen source for nitro reduction, but also a reductant for imine reduction. Secondary aromatic amines were obtained in the continuous flow reaction in good to excellent yields.

C–N Cross-coupling Reactions of Amines with Aryl Halides Using Amide-Based Pincer Nickel(II) Catalyst

Abstract: An approach to C–N cross-coupling reactions of aryl halides with amines in the presence of an amide-based pincer nickel(II) catalyst (2) is described. For 3?h reactions at 110?°C with 0.2?mol% catalyst, aryl bromides gave higher turnover numbers (TON) than the corresponding chlorides or iodides. Both primary and secondary amines could be used with the former giving higher TON. However, sterically hindered amines showed lower TON. In elucidating the mechanism of this nickel complex-catalyzed C–N cross coupling reaction it was found that the rate of reaction was unchanged in the presence of radical quenchers and a plausible Ni(I)–Ni(III) pathway is proposed. Graphic Abstract: [Figure not available: see fulltext.]Nickel pincer catalyst proved to be excellent catalyst for the C-N cross-coupling reaction with the high turnover number (TON) for 1° and 2° amines and different nonactivated aryl halides under optimum conditions.