30669-47-7Relevant articles and documents
Preparation of a Bi2WO6 catalyst and its catalytic performance in an alpha alkylation reaction under visible light irradiation
Liu, Xiaoling,Li, Haiying,Ma, Jingjing,Yu, Xiujuan,Wang, Yan,Li, Jingyi
, p. 157 - 166 (2019/01/28)
In this study, different types of Bi2WO6 catalysts were synthesized by a hydrothermal method using Bi(NO3)3?5H2O and Na2WO4?2H2O as precursors, and various characterization methods, such as X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), transmission electron microscopy (TEM), UV–vis diffuse reflectance spectroscopy (UV–vis DRS), Brunauer-Emmett-Teller (BET) specific surface area measurements, and photoluminescence (PL) analysis, were used to characterize the morphologies, structures, and valence states of the catalysts. Then, the catalysts were used to catalyze the alpha alkylation reaction of benzyl alcohol and acetophenone to obtain 1,3-diphenyl-1-propenone under visible light irradiation, and the photocatalytic reaction conditions were optimized. To expand the applicable range of alpha alkylation, the influence of different alcohols and different ketone derivatives on the photocatalytic reaction was determined. In addition, the effects of the wavelength and intensity of the light used were also important, and the recyclability of the catalyst and active species (such as superoxide radicals ([rad]O2?), holes (h+) and electrons (e?)) produced during the reaction were tested.
Synthesis of α,β-unsaturated ketones from alkynes and aldehydes over Hβ zeolite under solvent-free conditions
Mameda, Naresh,Peraka, Swamy,Kodumuri, Srujana,Chevella, Durgaiah,Banothu, Rammurthy,Amrutham, Vasu,Nama, Narender
, p. 58137 - 58141 (2016/07/07)
A facile Hβ zeolite-catalyzed strategy has been successfully developed for the synthesis of α,β-unsaturated ketones from alkynes and aldehydes under solvent-free conditions. The reaction proceeds via tandem hydration/condensation of alkynes with aldehydes to afford a range of α,β-unsaturated carbonyls in good to excellent yields. This journal is.
Claisen-schmidt condensation catalyzed by metal-organic frameworks
Dhakshinamoorthy, Amarajothi,Alvaro, Mercedes,Garcia, Hermenegildo
experimental part, p. 711 - 717 (2010/06/13)
Metal-organic framework [Fe(BTC) (BTC = 1,3,5-benzenetricarboxylic acid)] is a convenient heterogeneous catalyst for the carbon-carbon bond forming reaction in toluene between acetophenone and benzaldehyde to give selectively chalcone in high yield. Fe(BTC) appears as a general catalyst able to synthesize selectively different chalcone derivatives bearing various functionalities. Fe(BTC) could be recycled with no significant loss of catalytic efficiency and crystallinity in subsequent runs.