31089-73-3

Basic information

• Product Name: 3-Buten-1-one, 1-(2,6,6-trimethyl-1-cyclohexen-1-yl)-
• CAS NO: 31089-73-3
• Molecular Formula: C13H20O
• Molecular Weight: 192.301
• Mol File: 31089-73-3.mol

Chemical Properties

• CAS DataBase Reference: 3-Buten-1-one, 1-(2,6,6-trimethyl-1-cyclohexen-1-yl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Buten-1-one, 1-(2,6,6-trimethyl-1-cyclohexen-1-yl)-(31089-73-3)
• EPA Substance Registry System: 3-Buten-1-one, 1-(2,6,6-trimethyl-1-cyclohexen-1-yl)-(31089-73-3)

Safety Data

• Hazardous Substances Data: 31089-73-3(Hazardous Substances Data)

Upstream product

• 49815-59-0 4-(2',6',6'-trimethyl-1'-cyclohexenyl)-1,6-heptadien-4-ol 
• 49815-58-9 6,6-dimethyl-2-methyl-1-cyclohexene-1-carboxylic acid methyl ester 
• 28897-21-4 1-(2,2,6-trimethylcyclohex-1-ene-yl)but-3-en-1-ol 
• 13530-68-2 dichromic acid 
• 497-19-8 sodium carbonate 
• 432-25-7 2,6,6-trimethylcyclohex-1-enecarbaldehyde 

Downstream Products

• 53941-13-2 (E)-2-(2-butenyl)-1,3,3-trimethyl-1-cyclohexene 

Relevant articles and documents

NOVEL COMPOUND, AND METHOD FOR PRODUCING THE SAME, AND USE THEREOF

PROBLEM TO BE SOLVED: To provide a novel β-damascone derivative having stomach cancer cytostatic activity and β-secretase inhibitory action. SOLUTION: The present invention provides 10-hydroxy-β-damascone, represented by formula (2), which is a human meta

172. β-Cleavage of Bis(homoallylic) Potassium Alkoxides. Two-Step Preparation of Propenyl Ketones from Carboxylic Esters. Synthesis of ar-Turmerone, α-Damascone, β-Damascone, and β-Damascenone

The transformation of 36 bis(homoallylic) alcohols VII to alkenones IX and X via β-cleavage of their potassium alkoxides VIIa in HMPA has been investigated (cf.Scheme 2).These studies have established an order of β-cleavage for 2-propenyl, 1-methyl-2-propenyl, 2-methyl-2-propenyl, 1,1-dimethyl-2-propenyl, and benzyl groups in alkoxides 49a-56a and have allowed a comparison between the β-cleavage reaction and the oxy-Cope rearrangement in alkoxides 74a-83a.As illustrative synthetic applications, a two-step preparation of propenyl ketones 15-42 from carboxylic esters is described, together with syntheses of ar-turmerone (48), α-damascone ((E)-71), β-damascone ((E)-109), and β-damascenone ((E)-111).

Alkenoyl-cyclohexadienes

New cycloaliphatic unsaturated ketones and their use as perfuming and odour-modifying agents in the manufacture of perfumes and perfumed products, and as flavouring and taste-modifying agents in the preparation of foodstuffs in general and imitation flavours for foodstuffs, beverages, animal feeds, pharmaceutical preparations and tobacco products. Methods for the preparation of said cycloaliphatic unsaturated ketones.