32787-73-8

Basic information

• Product Name: 4-[(dimethylhydrazinylidene)methyl]-N,N-dimethylaniline
• CAS NO: 32787-73-8
• Molecular Formula: C₁₁H₁₇N₃
• Molecular Weight: 191.2728
• Mol File: 32787-73-8.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 322°C at 760 mmHg
• Flash Point: 148.5°C
• Density: 0.93g/cm³
• Vapor Pressure: 0.000288mmHg at 25°C
• Refractive Index: 1.509
• CAS DataBase Reference: 4-[(dimethylhydrazinylidene)methyl]-N,N-dimethylaniline(CAS DataBase Reference)
• NIST Chemistry Reference: 4-[(dimethylhydrazinylidene)methyl]-N,N-dimethylaniline(32787-73-8)
• EPA Substance Registry System: 4-[(dimethylhydrazinylidene)methyl]-N,N-dimethylaniline(32787-73-8)

Safety Data

• Hazardous Substances Data: 32787-73-8(Hazardous Substances Data)

Upstream product

• 57-14-7 N,N-Dimethylhydrazine 
• 100-10-7 4-dimethylamino-benzaldehyde 

Downstream Products

• 100-10-7 4-dimethylamino-benzaldehyde 

Relevant articles and documents

Perfluoroalkylation of Aryl-N,N-dimethyl Hydrazones Using Hypervalent Iodine(III) Reagents or Perfluoroalkyl Iodides

Radical trifluoromethylation of aryl N,N-dimethyl hydrazones using TBAI as an initiator and Togni's reagent as a trifluoromethyl radical source is described. Cascades proceed via electron-catalysis; this approach is generally more applicable to hydrazone perfluoroalkylation using perfluoroalkyl iodides as the radical precursors in combination with a base under visible-light initiation.

Synthesis of o -(dimethylamino)aryl ketones, acridones, acridinium salts, and 1 H -indazoles by the reaction of hydrazones and arynes

A novel, efficient route to biologically and pharmaceutically important o-(dimethylamino)aryl ketones, acridones, acridinium salts, and 1H-indazoles has been developed starting from readily available hydrazones of aldehydes and o-(trimethylsilyl)aryl triflates. The reaction proceeds through arynes under mild conditions, tolerates a wide range of functional groups, and provides the final products in good to excellent yields.