33734-57-5Relevant articles and documents
Optimization of chemo-enzymatic epoxidation of cyclohexene mediated by lipases
Moreira, Marcelo Alves,Bitencourt, Thiago Bergler,Nascimento, Maria Da Graca
, p. 2107 - 2114 (2005)
This work describes the lipase-mediated epoxidation of cyclohexene. Lipases were used to generate peroxyoctanoic acid directly from octanoic acid and hydrogen peroxide and applied in situ to obtain cyclohexene oxide. Various parameters, which could affect this reaction, were studied such as lipases from different sources, organic solvents, temperature and acyl donor concentrations. Highest conversions to cyclohexene epoxide were achieved using a two-phase system of toluene or xylene/water with ROL (Amano F-Ap15 free Rhizopus orizae lipase) (84 and 80%) or CALB (Novozymes 435-immobilized Candida antarctica lipase type B) (>9 and 84%) as biocatalysts. Using PSL (Amano PS-free Pseudomonas sp) the conversions were in the range of 12-53%, but an improvement was obtained by the use of the ionic liquid 1-butyl-3-methylimidazolium tetrafluoroborate (20 to 41% in water/methyl dichloride). Copyright Taylor & Francis, Inc.
Perdecanoic acid as a safe and stable medium-chain peracid for Baeyer-Villiger oxidation of cyclic ketones to lactones
Sitko, Magdalena,Szelwicka, Anna,Wojewódka, Andrzej,Skwarek, Andrzej,Tadasiewicz, Dariusz,Schimmelpfennig, Lech,Dziuba, Krzysztof,Morawiec-Witczak, Magdalena,Chrobok, Anna
, p. 30012 - 30018 (2019/10/02)
Stability studies dedicated to high-energy compounds for a series of linear peracids (C6-C12), including sensitivity to mechanical impulse (shock and friction), as well as electrical (spark) and thermal sensitivity (temperature and heat of decomposition), were presented in this work for the first time. Studies revealed that all peracids were insensitive to shock, while in the case of the other sensitivity tests sharp differences between results for C8 and C10 peracids were observed. Taking into account the relatively high initial temperature of decomposition (above 64 °C) perdecanoic acid was selected as a safe alternative to commonly used hazardous short-chain peracids. Next, a new method for the Baeyer-Villiger oxidation was presented. Oxidation of 2-adamantanone was chosen as a model reaction. Peroctanoic, perdecanoic and perdodecanoic acids were tested as oxidants. Peroctanoic acid was the most reactive but taking into account both safety and kinetic issues, perdecanoic acid was selected for the further studies. The influence of reaction conditions on reaction rate was investigated. Optimized reaction conditions were suggested (two-fold molar excess of peracid with respect to the ketone, toluene as a solvent, 35 °C). This exploratory study offers promise with regard to the development of safer alternatives to peracetic acid in industrial oxidation.
CONTINUOUS ON-LINE ADJUSTABLE DISINFECTANT/SANITIZER/BLEACH GENERATOR
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Page/Page column 21-22, (2012/07/14)
Methods and systems for on-site, continuous generation of peracid chemistry, namely peroxycarboxylic acids and peroxycarboxylic acid forming compositions, are disclosed. In particular, an adjustable biocide formulator or generator system is designed for on-site generation of peroxycarboxylic acids and peroxycarboxylic acid forming compositions from sugar esters. Methods of using the in situ generated peroxycarboxylic acids and peroxycarboxylic acid forming compositions are also disclosed.
METHODS FOR WASHING CARCASSES, MEAT, OR MEAT PRODUCTS WITH MEDIUM CHAIN PEROXYCARBOXLYIC ACID COMPOSITIONS
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Page/Page column 26, (2009/06/27)
The present invention relates to methods for reducing microbial contamination on carcass, meat, or meat product; or on surfaces used in processing the carcass, meat, or meat product; employing compositions including medium chain peroxycarboxylic acid, and to the compositions. The methods include applying a medium chain peroxycarboxylic acid composition to carcass, meat, meat product or surface.