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[Ph2SnCl(2-amino-1-cyclopentene-1-carbodithioate)] is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

356797-59-6

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356797-59-6 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 356797-59-6 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 3,5,6,7,9 and 7 respectively; the second part has 2 digits, 5 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 356797-59:
(8*3)+(7*5)+(6*6)+(5*7)+(4*9)+(3*7)+(2*5)+(1*9)=206
206 % 10 = 6
So 356797-59-6 is a valid CAS Registry Number.

356797-59-6Downstream Products

356797-59-6Relevant articles and documents

Synthesis, spectroscopic investigations and crystal structures of organotin(IV) derivatives of 2-amino-1-cyclopentene-1-carbodithioic acid

Tarassoli, Abbas,Sedaghat, Tahereh,Neumüller, Bernhard,Ghassemzadeh, Mitra

, p. 15 - 22 (2001)

The organotin(IV) chlorides RnSnCl4-n (n=2, R=nBu or Ph; and n=3, R=Ph) react with 2-amino-1-cyclopentene-1-carbodithioic acid (ACDA) to give [Ph2SnCl(ACDA)] (1), [Ph2Sn(ACDA)2] (2), [Ph3Sn(ACDA)] (3) and [Bu2Sn(ACDA)2] (4). The new complexes have been characterized by elemental analysis, UV-Vis, IR,1H NMR, 119Sn NMR spectroscopy and mass spectrometry. On the basis of 119Sn NMR data the effective coordination number in solution is five. The structures of 1, 3 and 4 have been confirmed by X-ray crystallography. Crystals of 1 are monoclinic with space group P21/n. The tin environment is distorted trigonal bipyramid with Cl and sulfur atoms in apical positions. Crystals of 3 are orthorombic, P212121, and the structure is distorted trigonal bipyramid with one sulfur and phenyl in the axial position. Complex 4 crystallizes in the triclinic space group, P1?, and the Sn atom shows extremely irregular octahedral coordination with four S atoms laying in the equatorial plane. In all complexes ACDA coordinates as an anisobidentate ligand and its orientation lends to form a NH···S intramolecular hydrogen bond. The packing is also stabilized by intermolecular hydrogen bonding.

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