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1135-99-5 Usage

Chemical Properties

white to off-white crystalline powder


Used in the manufacture of chemicals.

Check Digit Verification of cas no

The CAS Registry Mumber 1135-99-5 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 1,1,3 and 5 respectively; the second part has 2 digits, 9 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 1135-99:
65 % 10 = 5
So 1135-99-5 is a valid CAS Registry Number.

1135-99-5 Well-known Company Product Price

  • Brand
  • (Code)Product description
  • CAS number
  • Packaging
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  • Alfa Aesar

  • (71139)  Diphenyltin dichloride, 95%   

  • 1135-99-5

  • 2g

  • 160.0CNY

  • Detail
  • Alfa Aesar

  • (71139)  Diphenyltin dichloride, 95%   

  • 1135-99-5

  • 10g

  • 475.0CNY

  • Detail
  • Alfa Aesar

  • (71139)  Diphenyltin dichloride, 95%   

  • 1135-99-5

  • 50g

  • 2054.0CNY

  • Detail
  • Aldrich

  • (229202)  Diphenyltindichloride  96%

  • 1135-99-5

  • 229202-5G

  • 342.81CNY

  • Detail
  • Aldrich

  • (229202)  Diphenyltindichloride  96%

  • 1135-99-5

  • 229202-25G

  • 1,353.69CNY

  • Detail



According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017


1.1 GHS Product identifier

Product name Diphenyltin dichloride

1.2 Other means of identification

Product number -
Other names dichloro(diphenyl)stannane

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:1135-99-5 SDS

1135-99-5Relevant articles and documents

Diorganotin(IV) derivatives of dipeptides containing at least one essential amino acid residue: Synthesis, characteristic spectral data, cardiovascular, and anti-inflammatory activities

Nath, Mala,Pokharia, Sandeep,Eng, George,Song, Xueqing,Kumar, Ashok

, p. 1689 - 1708 (2004)

New diphenyltin(IV) derivatives of the formula Ph2SnL, where L is the dianion of glycyltryptophan (Gly-Trp), glycylphenylalanine (Gly-Phe), valylvaline (Val-Val), alanylvaline (Ala-Val), and leucylalanine (Leu-Ala), have been synthesized by the reaction of Ph2SnCl2 and the disodium salt of the respective dipeptides. The bonding and coordination behaviour in these derivatives are discussed on the basis of IR, multinuclear 1H, 13C, and 119Sn NMR and 119Sn Moessbauer spectroscopic studies. These investigations suggest that all the dipeptides in Ph2SnL act as dianionic tridentate ligands coordinating through the COO-, NH2, and Npeptide groups. The 119Sn Moessbauer studies, together with the NMR data, suggest a trigonal-bipyramidal geometry around tin in Ph2SnL with the phenyl groups and Npeptide in the equatorial positions, whereas a carboxylic oxygen and the amino nitrogen atom occupy the axial positions. The anti-inflammatory and cardiovascular activities, and toxicity of all the synthesized diphenyltin(IV) derivatives of dipeptides and of n-dibutyltin(IV) derivatives of dipeptides (synthesized and characterized earlier) viz. Gly-Trp, Val-Val, Ala-Val, glycyltyrosine (Gly-Tyr), leucyltyrosine (Leu-Tyr), and leucylleucine (Leu-Leu) are discussed. The n-dibutyltin(IV) derivatives exhibit better cardiovascular and anti-inflammatory activities than the diphenyltin(IV) analogues.


, p. L31 - L34 (1985)


An unusual reaction of (β-dimethylaminoethoxy)triethyltin with phenyltin trichloride. The first X-ray structural evidence of the existence of complexes R2SnXY·R2SnXY (R = Alkyl, Aryl; X, Y = Hal, OR, X ≠ Y) both as unsymmetrical addu

Portnyagin, Ivan A.,Nechaev, Mikhail S.,Khrustalev, Victor N.,Zemlyansky, Nikolay N.,Borisova, Irina V.,Antipin, Mikhail Yu.,Ustynyuk, Yuri A.,Lunin, Valery V.

, p. 4271 - 4277 (2006)

The substituent exchange reaction of PhSnCl3 with [Et 3Sn-(OCH2CH2NMe2)] gives rise unexpectedly to the unsymmetrical adduct [Ph2SnCl2· Ph2Sn(OCH2CH2/

Direct Detection, Dimerization, and Chemical Trapping of Dimethyl- and Diphenylstannylene from Photolysis of Stannacyclopent-3-enes in Solution

Duffy, Ian R.,Leigh, William J.

supporting information, p. 5029 - 5044 (2015/11/09)

Dimethyl- and diphenylstannylene (SnMe2 and SnPh2, respectively) have been successfully detected and characterized in solution. The stannylenes were generated by photolysis of 1,1,3-trimethyl-4-phenyl- (2) and 3,4-dimethyl-1,1-diphenylstannacyclopent-3-ene (3), respectively, which have been shown to extrude the species cleanly and in high (0.6 2SnCl2) as the stannylene substrate. Laser flash photolysis of 2 and 3 in deoxygenated hexanes affords promptly formed transient absorptions assigned to SnMe2 (λmax = 500 nm; ε500 = 1800 ± 600 M-1 cm-1) and SnPh2 (λmax = 290, 505 nm; ε500 = 2500 ± 600 M-1 cm-1), respectively, which decay with absolute second-order rate constants within a factor of 2 of the diffusional limit in both cases. The decay of the stannylenes is accompanied by the growth of new transient absorptions ascribable to the corresponding dimers, the structures of which are assigned with the aid of DFT and time-dependent (TD) DFT calculations at the (TD)ωB97XD/6-31+G(d,p)C,H,O-LANL2DZdpSn level of theory. Dimerization of SnMe2 affords a species exhibiting λmax = 465 nm, which is assigned to the expected Sn=Sn doubly bonded dimer, tetramethyldistannene (Me2Sn=SnMe2, 16a), in agreement with earlier work. In contrast, the spectrum of the dimer formed from SnPh2 exhibits strong absorptions in the 280-380 nm range and a very weak absorption at 650 nm, on the basis of which it is assigned to phenyl(triphenylstannyl)stannylene (17b). The calculations suggest that 17b is formed via ultrafast rearrangement of a novel phenyl-bridged stannylidenestannylene intermediate (20), which can be formed either directly by "endo" dimerization of SnPh2 or by isomerization of the "exo" dimer, tetraphenyldistannene (16b); the predicted barriers for these rearrangements are consistent with the experimental finding that the observed product is formed at close to the diffusion-controlled rate. Absolute rate and equilibrium constants are reported for the reactions of SnMe2 and SnPh2 with Me2SnCl2 and methanol (MeOH), respectively, in hexanes at 25 °C.

Tri- and diorganostannates containing 2-(N,N-dimethylaminomethyl)phenyl ligand

?vec, Petr,?erno?ková, Eva,Padělková, Zdeňka,R??i?ka, Ale,Hole?ek, Jaroslav

, p. 2475 - 2485 (2010/11/16)

The C,N-chelated tri and diorganotin(IV) chlorides react with both protic mineral acids and carboxylic acids. The nitrogen atom of the LCN ligand (where LCN is 2-(dimethylaminomethyl)phenyl) is thus quarternized - protonated and new Sn-X bond (X = Cl, Br, I or the remainder of the starting acid used) is simultaneously formed. The set of zwitterionic tri and diorganostannates containing protonated 2-(dimethylaminomethyl)phenyl-moiety was prepared and structurally characterized by multinuclear NMR spectroscopy and XRD techniques. In all these cases, the intramolecular N-H?X bond is present in the molecule. Despite the central tin atom remains five-coordinated (except for the [HLCNH]+[(n-Bu)2SnCl(NO 3)2]-) and reveals a distorted trigonal bipyramidal geometry, the 119Sn NMR chemical shift values of these zwitterionic stannates are somewhat shifted to the higher field than corresponding starting C,N-chelated tri and diorganotin(IV) halides. Reactions of C,N-chelated organotin(IV) halides with various Lewis acids are also discussed.

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