35890-85-8

Basic information

• Product Name: 2-<(2E,6E,10E,14E,18E,22E)-3,7,11,15,19,23-hexamethyltetracosa-2,6,10,14,18,22-hexaenyl>-1,4-benzoquinone
• Synonyms: 2-<(2E,6E,10E,14E,18E,22E)-3,7,11,15,19,23-hexamethyltetracosa-2,6,10,14,18,22-hexaenyl>-1,4-benzoquinone
• CAS NO: 35890-85-8
• Molecular Weight: 516.808
• Mol File: 35890-85-8.mol

Chemical Properties

• CAS DataBase Reference: 2-<(2E,6E,10E,14E,18E,22E)-3,7,11,15,19,23-hexamethyltetracosa-2,6,10,14,18,22-hexaenyl>-1,4-benzoquinone(CAS DataBase Reference)
• NIST Chemistry Reference: 2-<(2E,6E,10E,14E,18E,22E)-3,7,11,15,19,23-hexamethyltetracosa-2,6,10,14,18,22-hexaenyl>-1,4-benzoquinone(35890-85-8)
• EPA Substance Registry System: 2-<(2E,6E,10E,14E,18E,22E)-3,7,11,15,19,23-hexamethyltetracosa-2,6,10,14,18,22-hexaenyl>-1,4-benzoquinone(35890-85-8)

Safety Data

• Hazardous Substances Data: 35890-85-8(Hazardous Substances Data)

Upstream product

• 191401-76-0 (3E,7E)-2,10-Bis-benzenesulfonyl-2-[(E)-4-(5-methoxy-2-methoxycarbonyloxy-phenyl)-2-methyl-but-2-enyl]-4,8-dimethyl-10-((1E,5E)-2,6,10-trimethyl-undeca-1,5,9-trienyl)-undeca-3,7-dienedioic acid dimethyl ester 
• 191401-79-3 2-((2E,6E,10E,14E,18E)-5,13-Bis-benzenesulfonyl-3,7,11,15,19,23-hexamethyl-tetracosa-2,6,10,14,18,22-hexaenyl)-4-methoxy-phenol 
• 191401-72-6 (E)-2-Benzenesulfonyl-7-methoxycarbonyloxy-2-[(E)-4-(5-methoxy-2-methoxycarbonyloxy-phenyl)-2-methyl-but-2-enyl]-4,8-dimethyl-nona-3,8-dienoic acid methyl ester 
• 191401-71-5 (E)-2-Benzenesulfonyl-7-hydroxy-2-[(E)-4-(5-methoxy-2-methoxycarbonyloxy-phenyl)-2-methyl-but-2-enyl]-4,8-dimethyl-nona-3,8-dienoic acid methyl ester 
• 191401-70-4 (E)-2-Benzenesulfonyl-7-hydroxy-4,8-dimethyl-nona-3,8-dienoic acid methyl ester 
• 191401-69-1 (E)-8-Benzenesulfonyl-2,6-dimethyl-octa-1,6-dien-3-ol 
• 870-63-3 prenyl bromide 
• 159108-84-6 (3E,7E)-methyl 2-benzenesulfonyl-4,8,12-trimethyltrideca-3,7,11-trienoate 
• 159108-83-5 2-<2-<(methoxycarbonyl)oxy>-3-methylbut-3-enyl>-1-<(methoxycarbonyl)oxy>-4-methoxybenzene 
• 159108-82-4 2-(2-hydroxy-3-methyl-3-butenyl)-4-methoxyphenol 
• 144705-45-3 2-(2,3-Epoxy-3-methylbutyl)-4-methoxyphenol 
• 150-76-5 4-methoxy-phenol 
• 74832-85-2 6,7-oxido-3,7-dimethyl-1-(benzenesulfonyl)-(2E)-octene 
• 56881-53-9 (E,E)-farnesyl phenylsulfone 

Relevant articles and documents

Total synthesis of polyprenylhydroquinols and benzoquinones

The total synthesis of polyprenylhydroquinols and benzoquinones is described.First, two appropriate aromatic allyl carbonates (moieties with one and two prenyls) and two activated bifunctional terpenyl derivatives (moieties with two and three prenyls) were synthesized.These molecules were then reacted together using a highly regio- and stereoselective coupling with Pd(PPh3)4 as a catalyst.The synthesis was achieved by functional group elimination and formation of quinonic and hydroquinonic moieties. - Keywords: polyprenylbenzoquinol; polyprenylhydroquinone; allylcarbonate; ?-allyl palladium complex