144705-45-3

Upstream product

• 25974-58-7 4-methoxy-2-(3-methylbut-2-enyl)phenol 
• 870-63-3 prenyl bromide 
• 150-76-5 4-methoxy-phenol 

Downstream Products

• 22927-97-5 6-methoxy-2,2-dimethyl-2H-chromene 
• 159108-82-4 2-(2-hydroxy-3-methyl-3-butenyl)-4-methoxyphenol 
• 191487-99-7 C₇₃H₉₂O₁₆S₃ 
• 191487-98-6 (3E,7E)-2,10-Bis-benzenesulfonyl-10-((E)-5-methoxycarbonyloxy-2,6-dimethyl-hepta-1,6-dienyl)-2-[(E)-4-(5-methoxy-2-methoxycarbonyloxy-phenyl)-2-methyl-but-2-enyl]-4,8-dimethyl-undeca-3,7-dienedioic acid dimethyl ester 
• 191488-00-3 4-Methoxy-2-((2E,6E,10E,14E,18E,22E,26E)-5,13,21-tris-benzenesulfonyl-3,7,11,15,19,23,27,31-octamethyl-dotriaconta-2,6,10,14,18,22,26,30-octaenyl)-phenol 
• 191401-76-0 (3E,7E)-2,10-Bis-benzenesulfonyl-2-[(E)-4-(5-methoxy-2-methoxycarbonyloxy-phenyl)-2-methyl-but-2-enyl]-4,8-dimethyl-10-((1E,5E)-2,6,10-trimethyl-undeca-1,5,9-trienyl)-undeca-3,7-dienedioic acid dimethyl ester 
• 191487-97-5 (3E,7E)-2,10-Bis-benzenesulfonyl-10-((E)-5-hydroxy-2,6-dimethyl-hepta-1,6-dienyl)-2-[(E)-4-(5-methoxy-2-methoxycarbonyloxy-phenyl)-2-methyl-but-2-enyl]-4,8-dimethyl-undeca-3,7-dienedioic acid dimethyl ester 
• 191401-79-3 2-((2E,6E,10E,14E,18E)-5,13-Bis-benzenesulfonyl-3,7,11,15,19,23-hexamethyl-tetracosa-2,6,10,14,18,22-hexaenyl)-4-methoxy-phenol 
• 191401-72-6 (E)-2-Benzenesulfonyl-7-methoxycarbonyloxy-2-[(E)-4-(5-methoxy-2-methoxycarbonyloxy-phenyl)-2-methyl-but-2-enyl]-4,8-dimethyl-nona-3,8-dienoic acid methyl ester 
• 191401-71-5 (E)-2-Benzenesulfonyl-7-hydroxy-2-[(E)-4-(5-methoxy-2-methoxycarbonyloxy-phenyl)-2-methyl-but-2-enyl]-4,8-dimethyl-nona-3,8-dienoic acid methyl ester 
• 191401-84-0 2-((2E,6E,10E,14E,18E,22E,26E,30E)-3,7,11,15,19,23,27,31-octamethyldotriaconta-2,6,10,14,18,22,26,30-octaenyl)-4-methoxyphenol 
• 35890-90-5 2-octaprenyl-1,4-hydroquinone 
• 35890-87-0 2-((2E,6E,10E,14E,18E,22E,26E,30E)-3,7,11,15,19,23,27,31-octamethyldotriaconta-2,6,10,14,18,22,26,30-octaenyl)-1,4-benzoquinone 
• 191401-82-8 2-((2E,6E,10E,14E,18E,22E)-3,7,11,15,19,23-hexamethyltetracosa-2,6,10,14,18,22-hexaenyl)-4-methoxyphenol 

Relevant academic research and scientific papers

Total synthesis of polyprenylhydroquinols and benzoquinones

The total synthesis of polyprenylhydroquinols and benzoquinones is described.First, two appropriate aromatic allyl carbonates (moieties with one and two prenyls) and two activated bifunctional terpenyl derivatives (moieties with two and three prenyls) were synthesized.These molecules were then reacted together using a highly regio- and stereoselective coupling with Pd(PPh3)4 as a catalyst.The synthesis was achieved by functional group elimination and formation of quinonic and hydroquinonic moieties. - Keywords: polyprenylbenzoquinol; polyprenylhydroquinone; allylcarbonate; ?-allyl palladium complex

Total synthesis of 2-tetraprenylbenzoquinol and -benzoquinone

The total synthesis of 2-tetraprenylbenzoquinol and -benzoquinone is described. A key step in this synthesis is the highly regio- and stereoselective coupling between an appropriate aromatic allylcarbonate and an activated bifunctional farnesyl derivative

The chemistry of Lactarius fuliginosus and Lactarius picinus

Intact fruit-bodies of the Basidiomycetes Lactarius fuliginosus and L. picinus have been found to contain the stearic acid ester 4b. When the mushrooms are injured 4b is rapidly converted to the acrid free phenol 4a which is then gradually oxidized to a m