363172-06-9

Basic information

• Product Name: (2S,3S)-3-Benzyloxy-2-methyl-butyraldehyde
• Synonyms: (2S,3S)-3-Benzyloxy-2-methyl-butyraldehyde
• CAS NO: 363172-06-9
• Molecular Weight: 192.258
• Mol File: 363172-06-9.mol

Chemical Properties

• CAS DataBase Reference: (2S,3S)-3-Benzyloxy-2-methyl-butyraldehyde(CAS DataBase Reference)
• NIST Chemistry Reference: (2S,3S)-3-Benzyloxy-2-methyl-butyraldehyde(363172-06-9)
• EPA Substance Registry System: (2S,3S)-3-Benzyloxy-2-methyl-butyraldehyde(363172-06-9)

Safety Data

• Hazardous Substances Data: 363172-06-9(Hazardous Substances Data)

Upstream product

• 101470-81-9 (2R,3S)-1-Benzyloxymethyloxy-2-methylbutan-3-ol 
• 132409-48-4 (2RS,3SR)-3-O-benzyl-2-methyl-1,3-butanediol 
• 914461-68-0 (2R,3S)-3-hydroxy-2-methylbutyl-4-methylbenzenesulfonate 
• 100-39-0 benzyl bromide 
• 87678-97-5 anti-(2R,3S)-2-methylbutane-1,3-diol 

Downstream Products

• 565226-32-6 (2S,4S,5R,6R,7S,8S,9R,10S,11S)-11-Benzyloxy-2-{(4S,5R,6R)-6-[(S)-2-(tert-butyl-diphenyl-silanyloxy)-1-methyl-ethyl]-2,2,5-trimethyl-[1,3]dioxan-4-yl}-9-(4-methoxy-benzyloxy)-6,8,10-trimethyl-5,7-bis-triethylsilanyloxy-dodecan-4-ol 
• 565226-33-7 (S)-2-((4R,5R,6S)-6-{(S)-3-[(2S,4R,5R,6S)-6-[(1S,2R,3S,4S)-4-Benzyloxy-2-(4-methoxy-benzyloxy)-1,3-dimethyl-pentyl]-5-methyl-2-(2,4,6-trimethyl-phenyl)-[1,3]dioxan-4-yl]-1-methyl-but-3-enyl}-2,2,5-trimethyl-[1,3]dioxan-4-yl)-propan-1-ol 
• 565226-25-7 (R)-2-((4S,5R,6S)-6-{(S)-3-[(2S,4R,5R,6S)-6-((1S,2R,3R,4S)-4-Benzyloxy-2-hydroxy-1,3-dimethyl-pentyl)-5-methyl-2-(2,4,6-trimethyl-phenyl)-[1,3]dioxan-4-yl]-1-methyl-but-3-enyl}-2,2,5-trimethyl-[1,3]dioxan-4-yl)-propionic acid 
• 565226-37-1 C₄₂H₅₈O₉ 
• 565226-34-8 (1R,4S,5S,9S,10R,13R,14R,15S,17S,19R,20R)-13-((1S,2S)-2-Benzyloxy-1-methyl-propyl)-4,7,7,10,14,19,20-heptamethyl-2-methylene-17-(2,4,6-trimethyl-phenyl)-6,8,12,16,18-pentaoxa-tricyclo[13.3.1.1^5,9]icosan-11-one 
• 565226-36-0 C₄₀H₅₈O₈ 
• 1027918-84-8 (2S,5R,6R,7R,8R,9S,10S,11S)-11-Benzyloxy-2-[(4S,5R,6R)-6-((S)-2-hydroxy-1-methyl-ethyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-9-(4-methoxy-benzyloxy)-6,8,10-trimethyl-4-methylene-dodecane-5,7-diol 
• 565226-35-9 (1S,2R,5S,6R,7R,8R,9R,12S,13S,15S,17R)-5-((1S,2S)-2-Benzyloxy-1-methyl-propyl)-7,9-dihydroxy-2,6,8,12,17-pentamethyl-10-methylene-15-(2,4,6-trimethyl-phenyl)-4,14,16-trioxa-bicyclo[11.3.1]heptadecan-3-one 
• 565226-26-8 (2R,3R,4S,5S,6R,7S,8S)-8-Benzyloxy-6-(4-methoxy-benzyloxy)-3,5,7-trimethyl-2,4-bis-triethylsilanyloxy-nonanal 
• 565226-31-5 2,2-Dimethyl-propionic acid (2R,3S,4R,5S,6R,7S,8S)-8-benzyloxy-2-hydroxy-6-(4-methoxy-benzyloxy)-3,5,7-trimethyl-4-triethylsilanyloxy-nonyl ester 

Relevant articles and documents

The first stereoselective total synthesis of lankanolide. Part 2

The seco-acid derivative designed by conformation calculation and lactonization experiment of model seco-acids was synthesized, and subjected to macrolactonization to afford the lactone derivative. The lankanolide was synthesized via several steps after the lactonization, and the synthetic lankanolide was confirmed to have the same physical data (NMR, mass, IR and αD) as the lankanolide prepared from lankamycin according to the reported method.

Relative configuration of a δ-Lactone isolated from mandibular gland secretion of Calomyrmex sp. males

The relative configuration of a δ-lactone isolated from the mandibular gland extracts of Calomyrmex sp. males has been determined to be (3SR,5RS,6SR)-3,5,6-trimethyltetrahydropyran-2H-one after the synthesis of the four possible racemates and comparison o