38132-39-7Relevant articles and documents
Kinetics and mechanism of oxime formation from methyl benzoylformate
Malpica,Calzadilla
, p. 945 - 949 (2005)
Rate and equilibrium constants for methyl benzoylformate oxime formation were determined as a function of pH over the range from about 0 to 6. The reaction occurs with rate-determining carbinolamine dehydration over the entire range of pH investigated. Specific acid catalysis is dominant at pH 4. Above that value, a pH-independent reaction becomes apparent. This early appearance of an uncatalyzed reaction is interpreted as intramolecular assistance of the ester moiety in carbinolamine dehydration. Copyright
A New Polydentate Hydrazonic Ligand and its Dinuclear Copper(II) Complex with Different Co-Ordination Environments
Bacchi, Alessia,Battaglia, Luigi Pietro,Carcelli, Mauro,Pelizzi, Corrado,Pelizzi, Giancarlo,et al.
, p. 775 - 780 (2007/10/02)
A new hydrazone derivative, di-2-pyridyl ketone hydrazone (H2L), has been prepared and examined as a chelating agent towards metal ions.The molecular structure of the copper complex *H2O consists of a pair of structurally distinct metal centres with different environments bound to the heptadentate hydrazonic ligand and held together by a -N-N- bridge.