methyl benzoylformate semicarbazone

Base Information

• Chemical Name: methyl benzoylformate semicarbazone
• CAS No.: 38132-39-7
• Molecular Formula: C₁₀H₁₁N₃O₃
• Molecular Weight: 221.216
• Mol file: 38132-39-7.mol

Synonyms:methyl benzoylformate semicarbazone

Chemical Property of methyl benzoylformate semicarbazone

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of methyl benzoylformate semicarbazone

There total 5 articles about methyl benzoylformate semicarbazone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

methyl 2-oxo-2-phenylacetate (15206-55-0) + semicarbazide hydrochloride (563-41-7) → methyl benzoylformate semicarbazone (38132-39-7)

Guidance literature:

In methanol; water; for 1h; Heating;

DOI:10.1039/DT9930000775

Reference yield:

diazomethane (186581-53-3,908094-01-9,334-88-3) → methyl benzoylformate semicarbazone (38132-39-7)

Guidance literature:

With diethyl ether;

DOI:10.1021/ja01875a042

Reference yield:

2-oximino-2-phenylacetic acid methyl ester (24607-22-5) → methyl benzoylformate semicarbazone (38132-39-7)

Guidance literature:

Multi-step reaction with 2 steps

1: NH₂OH*HCl / methanol; H₂O / 30 °C

2: H₂O / 30 °C / pH 5.00

With hydroxylamine hydrochloride; In methanol; water;

DOI:10.1002/poc.932

upstream raw materials:

methyl 2-oxo-2-phenylacetate

semicarbazide hydrochloride

diazomethane

2-oximino-2-phenylacetic acid methyl ester

Downstream raw materials:

methyl 2-oxo-2-phenylacetate

semicarbazide hydrochloride

di-2-pyridyl ketone hydrazone