403501-36-0

Basic information

• Product Name: Oxirane, 2-(1-methylethyl)-2-phenyl-, (+)- (9CI)
• Synonyms: Oxirane, 2-(1-methylethyl)-2-phenyl-, (+)- (9CI)
• CAS NO: 403501-36-0
• Molecular Formula: C₁₁H₁₄O
• Molecular Weight: 162.22826
• Product Categories: ISOPROPYL
• Mol File: 403501-36-0.mol

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Oxirane, 2-(1-methylethyl)-2-phenyl-, (+)- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Oxirane, 2-(1-methylethyl)-2-phenyl-, (+)- (9CI)(403501-36-0)
• EPA Substance Registry System: Oxirane, 2-(1-methylethyl)-2-phenyl-, (+)- (9CI)(403501-36-0)

Safety Data

• Hazardous Substances Data: 403501-36-0(Hazardous Substances Data)

Upstream product

• 17498-71-4 3-methyl-2-phenyl-1-butene 
• 16282-55-6 2-(1-methylethyl)-2-phenyloxirane 

Relevant articles and documents

Isomerization of terminal epoxides by a [Pd-H] catalyst: A combined experimental and theoretical mechanistic study

An unusual palladium hydride complex has been shown to be a competent catalyst in the isomerization of a variety of terminal and internal epoxides. The reaction displayed broad scope and synthetic utility. Experimental and theoretical evidence are provided for an unprecedented hydride mechanism characterized by two distinct enantio-determining steps. These results hold promise for the development of an enantioselective variant of the reaction.

Asymmetric epoxidation catalyzed by α,α-dimethylmorpholinone ketone. Methyl group effect on spiro and planar transition states

(Chemical Equation Presented) Asymmetric epoxidation of olefins by using an α,α-dimethylmorpholinone-containing chiral ketone catalyst (4) has been investigated. This ketone, which has the combined features of several previously studied catalysts, is an effective catalyst for trans- and trisubstituted olefins, and up to 97% ee has been achieved. The R, R-dimethyl group has significant impact on spiro and planar transition states.