17498-71-4

Basic information

• Product Name: (2-Methyl-1-methylenepropyl)benzene
• Synonyms: (2-Methyl-1-methylenepropyl)benzene;3-Methyl-2-phenyl-1-butene;Benzene, (2-methyl-1-methylenepropyl)-;(3-Methylbut-1-En-2-Yl)Benzene(WXC02189);(3-METHYLBUT-1-EN-2-YL)BENZENE
• CAS NO: 17498-71-4
• Molecular Formula: C₁₁H₁₄
• Molecular Weight: 146.23
• Mol File: 17498-71-4.mol
• Article Data: 39

Chemical Properties

• Appearance: /
• CAS DataBase Reference: (2-Methyl-1-methylenepropyl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: (2-Methyl-1-methylenepropyl)benzene(17498-71-4)
• EPA Substance Registry System: (2-Methyl-1-methylenepropyl)benzene(17498-71-4)

Safety Data

• Hazardous Substances Data: 17498-71-4(Hazardous Substances Data)

Usage

General Description

(2-Methyl-1-methylenepropyl)benzene, also known as isopropenyltoluene, is a chemical compound with the molecular formula C10H12. It is an aromatic hydrocarbon that is commonly used as a precursor for the synthesis of various industrial chemicals. The compound is an important intermediate in the production of specialty polymers, resins, and coatings. It is also used as a fragrance ingredient in perfumes and personal care products. Additionally, (2-Methyl-1-methylenepropyl)benzene has been studied for its potential use as a fuel additive or as a component in high-performance lubricants. However, it is important to handle this chemical with care, as it can be harmful if ingested or inhaled and can cause irritation to the skin and eyes.

Upstream product

• 110-86-1 pyridine 
• 83867-61-2 2-chloro-3-methyl-2-phenyl butane 
• 563-80-4 3-methyl-butan-2-one 
• 33132-79-5 Dimethyl(2-phenyl-3-methylbutyl)amin 
• 13278-27-8 β-Hydroxy-β-phenyl-isocapronsaeure 
• 108-86-1 bromobenzene 
• 126300-67-2 (1-Methylene-butyl)-dipropyl-borane 
• 135086-30-5 Diisopropyl-(2-methyl-1-methylene-propyl)-borane 
• 13686-41-4 2,2-dimethyl-3-phenyl-3-butenoic acid 
• 75-11-6 diiodomethane 
• 611-70-1 phenyl isopropyl ketone 
• 20667-19-0 methyltriphenylphosphonium iodide 
• 1779-49-3 Methyltriphenylphosphonium bromide 
• 3262-89-3 triphenylboroxine 

Downstream Products

• 86766-19-0 (3S,5R)-3-Isopropyl-3,5-diphenyl-[1,2]dioxolane 
• 86766-18-9 (3S,5S)-3-Isopropyl-3,5-diphenyl-[1,2]dioxolane 
• 16282-55-6 2-(1-methylethyl)-2-phenyloxirane 
• 57441-31-3 2-(3-Methyl-2-phenyl-but-2-enyl)-malonic acid 
• 51559-18-3 (S)-(-)-3-methyl-2-phenylbutane-1,2-diol 
• 611-70-1 phenyl isopropyl ketone 
• 769-57-3 α,β,β-trimethylstyrene 
• 42238-03-9 (+/-)-3-methyl-2-phenylbut-2-yl hydroperoxide 
• 53172-83-1 2-methyl-3-phenyl-1-butene 
• 1177357-67-3 2-isopropyl-2-phenyloxirane 
• 403501-36-0 2-isopropyl-2-phenyloxirane 
• 2439-44-3 3-methyl-2-phenylbutanal 
• 1325729-44-9 (R)-4,4,5,5-tetramethyl-2-(3-methyl-2-phenylbutyl)-1,3,2-dioxaborolane 
• 51690-50-7 4-methyl-3-phenylpentanoic acid 

Relevant articles and documents

Chromato-mass-spectrometric identification using partition coefficients in the system of hexane-2,2,2-Trifluoroethanol

An additional characteristic of organic compounds, the partition coefficients in the heterophase solvent system n-hexane-2,2,2-trifluoroethanol, is shown to be useful for refining the results of chromatographic and gas chromatography-mass spectrometric identification. This opportunity is the most important for compounds that were not yet characterized by either mass spectra or chromatographic retention indices. Pleiades Publishing, Ltd., 2012.

Electrochemical fluorosulfonylation of styrenes

An environmentally friendly and efficient electrochemical fluorosulfonylation of styrenes has been developed. With the use of sulfonylhydrazides and triethylamine trihydrofluoride, a diverse array of β-fluorosulfones could be readily obtained. This reaction features mild conditions and a broad substrate scope, which could also be conveniently extended to a gram-scale preparation.

Stereoselective Synthesis of Vinylcyclopropa[ b]indolines via a Rh-Migration Strategy

A mild rhodium catalytic system has been developed to synthesize vinylcyclopropa[b]indolines through cyclopropanation of indoles with vinyl carbenoids generated from ring opening of cyclopropenes in situ. By employing a Rh-migration strategy, the products can be obtained with good to excellent E:Z ratios (≤99:1) and complete diastereoselectivity (≤99:1). This method is easy, has a low catalyst loading, and works for a broad range of functionalities.