4872-36-0Relevant articles and documents
P-stereogenic ferrocene-based (Trifluoromethyl)phosphanes: Synthesis, structure, coordination properties and catalysis
Sondenecker, Aline,Cvengros, Jan,Aardoom, Raphael,Togni, Antonio
, p. 78 - 87 (2011)
Diastereoselective ortho-hydroxymethylation of (R)-(1-ferrocenylethyl) dimethylamine and Bronsted-acid-mediatednucleophilic substitution with phenyl(trifluoromethyl)phosphane affords an epimeric mixture of P-stereogenic amine-phosphanes 4a and 4b, which a
Mild electrophilic trifluoromethylation of secondary and primary aryl- and alkylphosphines using hypervalent iodine(III)-CF3 reagents
Eisenberger, Patrick,Kieltsch, Iris,Armanino, Nicolas,Togni, Antonio
, p. 1575 - 1577 (2008/12/21)
A direct, mild and efficient trifluoromethylation of primary and secondary phosphines is achieved with easily accessible, cheap hypervalent iodine compounds acting as electrophilic CF3-transfer reagents. The Royal Society of Chemistry.