499140-12-4

Basic information

• Product Name: benzyl (2R,4S,5R)-4-methyl-5-phenyl-1,2,3-oxathiazolidine-2-oxide-3-carboxilate
• Synonyms: benzyl (2R,4S,5R)-4-methyl-5-phenyl-1,2,3-oxathiazolidine-2-oxide-3-carboxilate
• CAS NO: 499140-12-4
• Molecular Weight: 331.392
• Mol File: 499140-12-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: benzyl (2R,4S,5R)-4-methyl-5-phenyl-1,2,3-oxathiazolidine-2-oxide-3-carboxilate(CAS DataBase Reference)
• NIST Chemistry Reference: benzyl (2R,4S,5R)-4-methyl-5-phenyl-1,2,3-oxathiazolidine-2-oxide-3-carboxilate(499140-12-4)
• EPA Substance Registry System: benzyl (2R,4S,5R)-4-methyl-5-phenyl-1,2,3-oxathiazolidine-2-oxide-3-carboxilate(499140-12-4)

Safety Data

• Hazardous Substances Data: 499140-12-4(Hazardous Substances Data)

Upstream product

• 501-53-1 benzyl chloroformate 
• 492-41-1 (1R,2S)-norephedrine 
• 104863-92-5 (1R,2S)-1-phenyl-2-benzyloxycarbonylamino-1-propanol 

Downstream Products

• 70-29-1 diethyl sulphide 
• 499140-16-8 (1R,2S)-2-{[(benzyloxy)carbonyl]amino}-1-phenylpropyl (S)-2-methylpropane-2-sulfinate 
• 1115-15-7 divinyl sulfoxide 
• 2211-89-4 diisopropyl sulfoxide 
• 67-68-5 dimethyl sulfoxide 
• 104863-92-5 (1R,2S)-1-phenyl-2-benzyloxycarbonylamino-1-propanol 
• 1193-82-4 (S)-methylphenylsulfoxide 
• 4850-71-9 (R)-methyl phenyl sulfoxide 
• 82079-40-1 (S)-(2,4,6)-trimethylphenyl methyl sulfoxide 
• 20451-53-0 (-)-(S)_S-phenyl vinyl sulfoxide 
• 89299-86-5 (+)-(R)_S-phenyl vinyl sulfoxide 
• 4170-69-8 (R)-(isopropylsulfinyl)benzene 
• 80225-50-9 (S)-isopropyl phenyl sulfoxide 
• 128092-50-2 (+)-(R)-Ethyl p-Methoxyphenyl Sulfoxide 

Relevant articles and documents

A General and Expeditious One-Pot Synthesis of Sulfoxides in High Optical Purity from Norephedrine-Derived Sulfamidites

A general and simple procedure for preparing any kind of enantiomerically enriched sulfoxide starting from norephedrine-derived N-benzyloxycarbonylsulfamidite 3a is reported. After one-pot reaction of 3a with RMgX, HBF4, and R'MgX, a variety of sulfoxides 6 are obtained in ee usually higher than 93% and isolated yields ranging between 50 and 78%. The obtained configuration is tunable by simply electing the order of the addition of the reagents.