4170-69-8Relevant articles and documents
Practical synthesis of active O-2-(2-propylsulfinyl)benzyl (OPSB) glycosides via a catalytic and metal free oxidation of latent O-2-(2-propylthiol)benzyl (OPTB) glycosides
Xiao, Ying,Lu, Zimin,Zhao, Xiang,Wu, Pingru,Chen, Wei,Wang, Ruobing,Zeng, Jing,Wan, Qian
, p. 10 - 13 (2018)
A catalytic and metal free sulfoxidation of O-2-(2-propylthiol)benzyl (OPTB) glycosides to O-2-(2-propylsulfinyl)benzyl (OPSB) glycosides has been developed by introducing NOBF4 as catalyst, oxygen as terminal oxidant and TBAB as additive. Wide
Micellar catalysis on the electron transfer reactions of iron(III)-polypyridyl complexes with organic sulfides - Importance of hydrophobic interactions
Balakumar,Thanasekaran,Rajkumar,Adaikalasamy, K. John,Rajagopal,Ramaraj,Rajendran,Manimaran,Lu
, p. 352 - 358 (2006)
The oxidation of organic sulfides with iron(iii)-polypyridyl complexes [Fe(NN)3]3+ proceeds through an electron transfer mechanism and an increase in the methanol content in the methanol-water mixture favors the reaction. The reactio
Selective Catalytic Oxidation of Organic Sulfides to Sulfoxides without Forming Sulfones over Solid Molybdenum Blue: Kinetic and Thermodynamic Studies
Ratheshkumar,Induja,Raghavan
, p. 2267 - 2274 (2020/09/16)
The present investigation reports studies on the selective catalytic oxidation of organic sulfide substrates over molybdenum blue catalyst supported on boron phosphate. The catalyst was synthesized through partial precipitation method and characterized by
Polymer-supported eosin Y as a reusable photocatalyst for visible light mediated organic transformations
Sridhar, Arunasalam,Rangasamy, Rajmohan,Selvaraj, Mari
, p. 17974 - 17979 (2019/12/02)
A novel polymer-supported recyclable photocatalyst has been developed for visible light mediated oxidation reactions. The organic dye eosin Y was loaded on macroporous commercially available Amberlite IRA 900 chloride resin and exploited as a photocatalyst for visible light mediated oxidation of thioethers to sulfoxides and phenylboronic acids to phenols under open atmospheric air. Varieties of functional groups were well tolerated during oxidation. The catalyst is recyclable for six cycles without significant loss in its efficiency. Furthermore, gram-scale oxidation of sulfides to sulfoxides has been demonstrated to prove the commercial viability of the method.