5032-93-9Relevant articles and documents
Bis(pentafluorophenyl)phosphinous acid in the synthesis of P,P-bis(pentafluorophenyl)phosphorylalkanones and -alkanediones
Goryunov,Goryunova,Nelyubina, Yu. V.,Frolova,Savin,Strelkova,Pasechnik,Brel
, p. 2317 - 2324 (2015/06/22)
Addition of bis(pentafluorophenyl)phosphinous acid to α,β-alkenones and α,β,β'-alkene-diones in anhydrous Et2O (the solvent, in which the P-OH tautomeric form predominates) proceeds rapidly and regiospecifically at the C=C bond of the substrate
Synthesis and characterization of some perfluorophenylphosphine derivatives
Magnelli,Tesi,Lowe Jr.,Mcquistion
, p. 457 - 461 (2008/10/08)
Bis(pentafluorophenyl)chlorophosphine and pentafluorophenyldichlorophosphine are prepared in good yields from pentafluorophenylmagnesium bromide and phosphorus trichloride. The reactions of the halophosphines with the Lewis bases water, ammonia, dimethylamine, and 2-methylaziridine produced substituted phosphines. Oxidative chlorination of bis(pentafluorophenyl)phosphinamide followed by dehydrohalogenation gave perfluorophenylphosphonitriles. The infrared and pertinent proton magnetic resonance spectra of these compounds are discussed.
