53416-89-0Relevant articles and documents
An Efficient Route to the Tropane Alkaloids
Mann, John,Barbosa, Luiz-Claudio de Almeida
, p. 787 - 790 (2007/10/02)
We describe the use of diethylzinc in conjunction with polybromo ketones for the production of oxyallyls, and the interception of these intermediates by furans and methyl pyrrole-N-carboxylate.This methodology allows the production of gramme quantities of tropane alkaloids, and 2-substituted 8-oxabicyclooct-6-en-3-ones that have been either difficult or impossible to prepare.